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Using curved arrows, show the mechanism of each step labeled with a blue letter. Draw out abbreviated structures of the coenzymes, so that you can effectively show all arrow pushing. You may abbreviate the coenzymes by putting R groups on the molecule, but do draw out the parts of the structure that are involved in the arrow pushing. Please note that some of the transformations will require you to show multiple structures to show all of the arrow pushing (particularly some of the coenzyme-mediated steps). You do not need to show specific amino acid residues that perform the catalysis. You can abbreviate acidic amino acid residues “Enz–B–H” and basic residues “B­–Enz”.

Using curved arrows, show the mechanism of each step labeled with a blue letter. Draw out abbreviated structures of the coenzymes, so that you can effectively show all arrow pushing. You may abbreviate the coenzymes by putting R groups on the molecule, but do draw out the parts of the structure that are involved in the arrow pushing. Please note that some of the transformations will require you to show multiple structures to show all of the arrow pushing (particularly some of the coenzyme-mediated steps). You do not need to show specific amino acid residues that perform the catalysis. You can abbreviate acidic amino acid residues “Enz–B–H” and basic residues “B­–Enz”.

Biochemistry
Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
Section: Chapter Questions
Problem 1P
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Using curved arrows, show the mechanism of each step labeled with a blue letter. Draw out abbreviated structures of the coenzymes, so that you can effectively show all arrow pushing. You may abbreviate the coenzymes by putting R groups on the molecule, but do draw out the parts of the structure that are involved in the arrow pushing.

Please note that some of the transformations will require you to show multiple structures to show all of the arrow pushing (particularly some of the coenzyme-mediated steps). You do not need to show specific amino acid residues that perform the catalysis. You can abbreviate acidic amino acid residues “Enz–B–H” and basic residues “B­–Enz”.

2-O,POO_CO CH₂ H2O НО- -Н НИ Н- (A) -ОН Н- -OH CH2OPO32- H Н -OH Н -OH CH₂OPO3²- CH₂ HO-H + H-OH Н- -OH CH₂OPO3²- 2-03РО. (D) 2-3рон2 HO CO а 해 OH NAD+ NADH (E) (B) 2-03P0-+-co, CH₂ 2-О РОН2С HO CO₂ CO₂ HO CO₂ NADH NAD+ да се от два OH OH OH OH НО -Н Н OH H-OH OH (H) CH₂OPO3²- HO CO2 OH но, со OH (C) P₁ OH
Transcribed Image Text:2-O,POO_CO CH₂ H2O НО- -Н НИ Н- (A) -ОН Н- -OH CH2OPO32- H Н -OH Н -OH CH₂OPO3²- CH₂ HO-H + H-OH Н- -OH CH₂OPO3²- 2-03РО. (D) 2-3рон2 HO CO а 해 OH NAD+ NADH (E) (B) 2-03P0-+-co, CH₂ 2-О РОН2С HO CO₂ CO₂ HO CO₂ NADH NAD+ да се от два OH OH OH OH НО -Н Н OH H-OH OH (H) CH₂OPO3²- HO CO2 OH но, со OH (C) P₁ OH
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Could you help me with the remaind of the reactions F to H? See picture of the mechanism below. 

0 Н Н H -ОН -OH CH2OPO32- О НО- Н- Н CO₂ CH₂ -Н -ОН + OH CH2OPO32- 2-О3РО OH (D) CO₂ 2-O3РОН2С (A) HO CO₂ OH CH₂ -H H -OH H НО OH -OH CH₂OPO3²- H2O NAD+ (E) (B) NADH HO CO₂ HO CO₂ NADH NAD+ ферме OH OH HO CO₂ таки 2-О3РОН2С OH CO₂ 2-03РО- OH OH OH Ө -CO₂ CH₂ Н НО -Н -OH Н- -ОН CH2OPO32- (H) P₁ А (C) OH (F) Ө HO CO₂ P₁ OH
Transcribed Image Text:0 Н Н H -ОН -OH CH2OPO32- О НО- Н- Н CO₂ CH₂ -Н -ОН + OH CH2OPO32- 2-О3РО OH (D) CO₂ 2-O3РОН2С (A) HO CO₂ OH CH₂ -H H -OH H НО OH -OH CH₂OPO3²- H2O NAD+ (E) (B) NADH HO CO₂ HO CO₂ NADH NAD+ ферме OH OH HO CO₂ таки 2-О3РОН2С OH CO₂ 2-03РО- OH OH OH Ө -CO₂ CH₂ Н НО -Н -OH Н- -ОН CH2OPO32- (H) P₁ А (C) OH (F) Ө HO CO₂ P₁ OH
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