Consider the two sets of Newman projections for 2,3-dibromobutane. Br H OOC HC CH, A (R, R) diastereomers Br H Oenantiomers O identical molecules H Br Select the relationship between molecules A and B. HC CH B (S, S) Br Br Br HỌC CH, с (R, S) H H H diastereomers H O enantiomers O identical molecules HỌC CH, D (S, R) Br Select the relationship between molecules C and D. Br
Consider the two sets of Newman projections for 2,3-dibromobutane. Br H OOC HC CH, A (R, R) diastereomers Br H Oenantiomers O identical molecules H Br Select the relationship between molecules A and B. HC CH B (S, S) Br Br Br HỌC CH, с (R, S) H H H diastereomers H O enantiomers O identical molecules HỌC CH, D (S, R) Br Select the relationship between molecules C and D. Br
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:## Newman Projections for 2,3-Dibromobutane
### Overview:
The image presents four Newman projections for 2,3-dibromobutane, a common study model in organic chemistry to understand stereochemistry. These projections illustrate different spatial arrangements of atoms when viewing along the bond between the second and third carbon atoms.
### Detailed Explanation of Projections:
**Molecule A (R, R)**:
- The front carbon (C2) has substituents: H, Br, and CH3.
- The rear carbon (C3) has substituents: H, Br, and CH3.
- Both chiral centers are in the R configuration.
**Molecule B (S, S)**:
- The front carbon (C2) has substituents: H, Br, and CH3.
- The rear carbon (C3) has substituents: H, Br, and CH3.
- Both chiral centers are in the S configuration.
**Molecule C (R, S)**:
- The front carbon (C2) has substituents: H, Br, and CH3.
- The rear carbon (C3) has substituents: H, Br, and CH3.
- The chiral center on the front carbon is in the R configuration.
- The chiral center on the rear carbon is in the S configuration.
**Molecule D (S, R)**:
- The front carbon (C2) has substituents: H, Br, and CH3.
- The rear carbon (C3) has substituents: H, Br, and CH3.
- The chiral center on the front carbon is in the S configuration.
- The chiral center on the rear carbon is in the R configuration.
### Questions:
#### Select the relationship between molecules A and B:
- Diastereomers
- Enantiomers
- Identical molecules
#### Select the relationship between molecules C and D:
- Diastereomers
- Enantiomers
- Identical molecules
### Explanation of Questions:
- **Enantiomers** are a pair of molecules that are non-superimposable mirror images of each other, having opposite configurations at each chiral center.
- **Diastereomers** are stereoisomers that are not mirror images of each other and hence have different configurations at one or more (but not all) chiral centers.
- **Identical molecules** are molecules that
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