Consider the following two reactions. Which is more highly regioselective, and why? Reaction 1 `Cl + HCl Reaction 2 + HCl `Cl O Reaction 1, because the regioselectivity is determined by the difference in E, leading to a 1° versus a 3° carbocation, while in Reaction 2, both products are formed from a 3° carbocation. O They should have exactly the same regioselectivity, because both reactions can give 1-chloro-1- methylcyclohexane. O Reaction 1, because the regioselectivity is determined by the difference in Ea leading to a 1° versus a 3° carbocation, which is greater than the difference in E, leading to a 2° versus a 3° carbocation. O Reaction 1, because the regioselectivity is determined by the difference in Ea leading to a 1° versus a 2° carbocation, which is greater than the difference in E, leading to a 2° versus a 3° carbocation. Reaction 2, because the regioselectivity is determined by the difference in Ea leading to a 2° versus a 3° carbocation, which is greater than the difference in Ea leading to a 1° versus a 3° carbocation.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question
Consider the following two reactions. Which is more highly regioselective, and why?
Reaction 1
`Cl
+ HCl
Reaction 2
+ HCl
`Cl
Reaction 1, because the regioselectivity is determined by the difference in E, leading to a 1° versus a 3°
carbocation, while in Reaction 2, both products are formed from a 3° carbocation.
O They should have exactly the same regioselectivity, because both reactions can give 1-chloro-1-
methylcyclohexane.
Reaction 1, because the regioselectivity is determined by the difference in Ea leading to a 1° versus a 3°
carbocation, which is greater than the difference in Ea leading to a 2° versus a 3° carbocation.
Reaction 1, because the regioselectivity is determined by the difference in Ea leading to a 1° versus a 2°
carbocation, which is greater than the difference in Ea leading to a 2° versus a 3° carbocation.
O Reaction 2, because the regioselectivity is determined by the difference in Ea leading to a 2° versus a 3°
carbocation, which is greater than the difference in E, leading to a 1° versus a 3° carbocation.
Transcribed Image Text:Consider the following two reactions. Which is more highly regioselective, and why? Reaction 1 `Cl + HCl Reaction 2 + HCl `Cl Reaction 1, because the regioselectivity is determined by the difference in E, leading to a 1° versus a 3° carbocation, while in Reaction 2, both products are formed from a 3° carbocation. O They should have exactly the same regioselectivity, because both reactions can give 1-chloro-1- methylcyclohexane. Reaction 1, because the regioselectivity is determined by the difference in Ea leading to a 1° versus a 3° carbocation, which is greater than the difference in Ea leading to a 2° versus a 3° carbocation. Reaction 1, because the regioselectivity is determined by the difference in Ea leading to a 1° versus a 2° carbocation, which is greater than the difference in Ea leading to a 2° versus a 3° carbocation. O Reaction 2, because the regioselectivity is determined by the difference in Ea leading to a 2° versus a 3° carbocation, which is greater than the difference in E, leading to a 1° versus a 3° carbocation.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Aromatic Compounds
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY