Answer the following questions about each reaction scheme shown below: Br d t-BuOK This is NOT the correct product for this reaction. Provide the name of the correct product: What is the mechanism that gives the correct product (answer SN2, SN1, E1, or E2): Br OC(CH3)3 b. t-BuOH This is NOT the correct product for this reaction. Provide the name of the correct product: What is the mechanism that gives the correct product (answer SN2, SN1, E1, or E2): a.
Answer the following questions about each reaction scheme shown below: Br d t-BuOK This is NOT the correct product for this reaction. Provide the name of the correct product: What is the mechanism that gives the correct product (answer SN2, SN1, E1, or E2): Br OC(CH3)3 b. t-BuOH This is NOT the correct product for this reaction. Provide the name of the correct product: What is the mechanism that gives the correct product (answer SN2, SN1, E1, or E2): a.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![### Reaction Schemes and Mechanism Analysis
#### a.
![Chemical Structure]
A cyclohexane molecule with a bromide (Br) substituent.
Reactant: Bromocyclohexane
Reagent: t-BuOK (tert-Butoxide)
**Reaction Outcome**
This is **NOT** the correct product for this reaction.
**Questions:**
1. Provide the name of the correct product:
- **Answer:**
2. What is the mechanism that gives the correct product (answer SN2, SN1, E1, or E2):
- **Answer:**
#### b.
![Chemical Structure]
A cyclohexane molecule with a bromide (Br) substituent.
Reactant: Bromocyclohexane
Reagent: t-BuOH (tert-Butanol)
**Reaction Outcome**
This is **NOT** the correct product for this reaction.
**Questions:**
1. Provide the name of the correct product:
- **Answer:**
2. What is the mechanism that gives the correct product (answer SN2, SN1, E1, or E2):
- **Answer:**](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffdac5784-6171-4c2d-813f-cbb526f56bfb%2F90eb51bf-d884-4903-a678-23e542b3d335%2F3tnq6mb_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Reaction Schemes and Mechanism Analysis
#### a.
![Chemical Structure]
A cyclohexane molecule with a bromide (Br) substituent.
Reactant: Bromocyclohexane
Reagent: t-BuOK (tert-Butoxide)
**Reaction Outcome**
This is **NOT** the correct product for this reaction.
**Questions:**
1. Provide the name of the correct product:
- **Answer:**
2. What is the mechanism that gives the correct product (answer SN2, SN1, E1, or E2):
- **Answer:**
#### b.
![Chemical Structure]
A cyclohexane molecule with a bromide (Br) substituent.
Reactant: Bromocyclohexane
Reagent: t-BuOH (tert-Butanol)
**Reaction Outcome**
This is **NOT** the correct product for this reaction.
**Questions:**
1. Provide the name of the correct product:
- **Answer:**
2. What is the mechanism that gives the correct product (answer SN2, SN1, E1, or E2):
- **Answer:**
![**Transcription of the Image for Educational Purposes**
---
**c.**
![Reaction scheme]
\[
\text{CH\(_3\) - C(Br)(CH\(_3\)) - CH\(_3\)}
\xrightarrow{\text{NaCN}}
\text{CH\(_3\) - C(CN)(CH\(_3\)) - CH\(_3\)}
\]
This product **IS** correct, and it is a good example of the _______ inversion.
What is the mechanism that gives this product (answer SN2, SN1, E1, or E2): _______
---
**d.**
![Reaction scheme]
\[
\text{CH\(_3\) - C(Br)(CH\(_3\)) - CH\(_3\)}
\xrightarrow{\text{EtOH, heat}}
\text{CH\(_3\) - C(OEt)(CH\(_3\)) - CH\(_3\)}
\]
This reaction **IS** drawn correctly. What is the mechanism that gives this product (answer SN2, SN1, E1, or E2): _______
This reaction is also a good example of 1,2-_______ shift rearrangement.
---
**e.**
![Reaction scheme]
\[
\text{CH\(_3\) - CH\(_2\) - CH\(_2\) - C(Br)(CH\(_3\)) - CH\(_3\)}
\xrightarrow{\text{NaOCH\(_3\)}}
\text{CH\(_3\) - CH\(_2\) - CH\(_2\) - C(OCH\(_3\))(CH\(_3\)) - CH\(_3\)}
\]
This is **NOT** the correct product for this reaction. What is the absolute configuration of the chiral carbon in the correct product (R, S, racemic, or achiral)? _______
What is the mechanism that gives this product (answer SN2, SN1, E1, or E2): _______
---
**Explanation of Graphs and Diagrams:**
1. **Reaction scheme (c):**
- Represents a substitution reaction where a bromine (Br) atom is replaced by a cyanide (CN) group.
2. **Reaction scheme (d):**
- Shows a substitution reaction where a](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffdac5784-6171-4c2d-813f-cbb526f56bfb%2F90eb51bf-d884-4903-a678-23e542b3d335%2Fbaiw0d_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Transcription of the Image for Educational Purposes**
---
**c.**
![Reaction scheme]
\[
\text{CH\(_3\) - C(Br)(CH\(_3\)) - CH\(_3\)}
\xrightarrow{\text{NaCN}}
\text{CH\(_3\) - C(CN)(CH\(_3\)) - CH\(_3\)}
\]
This product **IS** correct, and it is a good example of the _______ inversion.
What is the mechanism that gives this product (answer SN2, SN1, E1, or E2): _______
---
**d.**
![Reaction scheme]
\[
\text{CH\(_3\) - C(Br)(CH\(_3\)) - CH\(_3\)}
\xrightarrow{\text{EtOH, heat}}
\text{CH\(_3\) - C(OEt)(CH\(_3\)) - CH\(_3\)}
\]
This reaction **IS** drawn correctly. What is the mechanism that gives this product (answer SN2, SN1, E1, or E2): _______
This reaction is also a good example of 1,2-_______ shift rearrangement.
---
**e.**
![Reaction scheme]
\[
\text{CH\(_3\) - CH\(_2\) - CH\(_2\) - C(Br)(CH\(_3\)) - CH\(_3\)}
\xrightarrow{\text{NaOCH\(_3\)}}
\text{CH\(_3\) - CH\(_2\) - CH\(_2\) - C(OCH\(_3\))(CH\(_3\)) - CH\(_3\)}
\]
This is **NOT** the correct product for this reaction. What is the absolute configuration of the chiral carbon in the correct product (R, S, racemic, or achiral)? _______
What is the mechanism that gives this product (answer SN2, SN1, E1, or E2): _______
---
**Explanation of Graphs and Diagrams:**
1. **Reaction scheme (c):**
- Represents a substitution reaction where a bromine (Br) atom is replaced by a cyanide (CN) group.
2. **Reaction scheme (d):**
- Shows a substitution reaction where a
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