Consider the following mechanism for the reduction of nitric oxide: H,(g) + 2 NO(g) - N,0(g) + H,O(g) (1) H,(9) + N,0(g) N2(9) + H,O(g) (2) Write the chemical equation of the overall reaction: yes Are there any intermediates in this mechanism? O no If there are intermediates, write down their chemical formulas. Put a comma between each chemical formula, if there's more than one.

Consider the following mechanism for the reduction of nitric oxide: H,(g) + 2 NO(g) - N,0(g) + H,O(g) (1) H,(9) + N,0(g) N2(9) + H,O(g) (2) Write the chemical equation of the overall reaction: yes Are there any intermediates in this mechanism? O no If there are intermediates, write down their chemical formulas. Put a comma between each chemical formula, if there's more than one.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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1. The mechanism of a certain non-elementary reaction is given below: (1) NO2Cl = NO2 + Cl k1, k-1 (2) Cl + NO2Cl → NO2 + Cl2 k2 derive (a) Using the steady-state approximation, the differential rate law for the formation of molecular chlorine, Cl2, as a function of time on the basis of the above mechanism.
Consider the following mechanism for the oxidation of carbon monoxide:
Consider the following mechanism for the formation of nitrpgen dioxide: 2 NO(g) → N,O2(9) (1) N2O2(9) + O2(g) –→ 2 NO2(g) (2) Write the chemical equation of the overall reaction: O yes Are there any intermediates in this mechanism? O no If there are intermediates, write down their chemical formulas. Put a comma between each chemical formula, if there's more than one.
The decomposition reaction of ammonia gas (NH3) into hydrogen gas (H2) and nitrogen (N2) with a Pt catalyst is a zero order reaction at a temperature of 1130 K (i) rate of reaction = rate constant,(ii) reaction rate depends on ammonia concentration,(iii) the rate of decomposition of ammonia becomes constant when the ammonia has completely reacted,(iv) an increase in gas pressure will change the rate of the reaction. A. (ii) and (iv)B. (i) and (ii)C. (i), (ii) and (iii)D. (ii), (iii) and (iv)E. (i), (iii) and (iv)
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A reaction is described as follows: k1 X + Y The table below shown the initial rates of the formation of product Z (Vo) for various reactant concentrations. From the data given, answer the followings: [X], mol L- [Y], mol L-1 34 Vo (x 103 mol L-s') 22 1.00 70 45 4.20 8.08 71 89 (i) The rate law of formation of product Z, (ii) The overall rate order and the order with respect to each component, and (iii) The rate constant (state clearly its units and coefficients).
The following mechanism has been proposed for the atmospheric destruction of ozone, O3 (g):O3 (g) + NO (g) --> O2 (g) + NO2 (g) (slow)NO2 (g) + O (g) --> NO (g) + O2 (g) (fast)a) Write the equation for the overall balanced reaction. b) Write the rate law predicted by this reaction mechanism.
Consider the mechanism: NO2(8) + SO2(g) → NO(g) + SO3(g) NO(g) + ½ O2(g) –→ NO2(g)
Suggest a mechanism behind the reaction NO(g) + Cl2(g) à NOCl(g) + Cl(g) with the rate law rate = k [NO]2 [Cl2] This reaction cannot be a one step reaction because of its rate law. It is therefore a multistep reaction, where the slow step represents a reaction between 2 molecules of NO with one molecule of Cl2 (slow) 2NO + Cl2 à ………. (fast). à ………… NO + Cl2. à NOCl + Cl
The following mechanism has been proposed for the reaction of H2 (g) and NO (g): H2 (g) + NO (g) → H2O (g) + N (g) (Slow)N (g) + NO (g) → N2 (g) + O (g) (Fast)H2 (g) + O (g) → H2O (g) (Fast)a) Write the equation for the overall balanced reaction. b) Write the rate law predicted by this reaction mechanism.
The decomposition of hydrogen peroxide in dilute sodium hydroxide at 20 °C H,O2(aq)H,0() + ½ O2(g) is first order in H20, with a rate constant of 1.10x10-3 min!. If the initial concentration of H,O, is 6.48×10-2 M, the concentration of H,O, will be 1.17x10-2 M after min have passed.
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