Consider the cyclohexane below. CH3 Part 1 of 3 H₂C H₂C H₂C 6 ... 4 CH3 Use the cyclohexane conformation drawing tool and guide points to draw the given cyclohexane. Be sure to draw each substituent in the same positi number on the chair conformation. H₂C H₁₂C CH3 HC CH₂3 Use the cyclohexane conformation drawing tool and guide points to draw the result of the ring inversion of the original chair conformation from Part 1.

Consider the cyclohexane below. CH3 Part 1 of 3 H₂C H₂C H₂C 6 ... 4 CH3 Use the cyclohexane conformation drawing tool and guide points to draw the given cyclohexane. Be sure to draw each substituent in the same positi number on the chair conformation. H₂C H₁₂C CH3 HC CH₂3 Use the cyclohexane conformation drawing tool and guide points to draw the result of the ring inversion of the original chair conformation from Part 1.

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter7: Cycloalkanes

Section: Chapter Questions

Problem 17E: Build a model of methylcyclohexane, and use the model to complete the following Newmanprojections of...

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Consider 1-bromo-2-methylpropane and draw the following. (a) The staggered conformation(s) of lowest energy (b) The staggered conformation(s) of highest energy
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Build a model of methylcyclohexane, and use the model to complete the following Newmanprojections of methylcyclohexane in the chair conformation: a. When the methyl group is in an axial or equatorial (circle one) position, the molecule is inits lowest potential energy conformation. b. Label one Newman projection above anti and the other gauche to describe the relationshipbetween the methyl group and C3 of the ring. c. In general, which is a lower PE conformation, anti or gauche? d. Explain how your answer to b and c provide an explanation for why it is more favorable fora large group to be in an equatorial than an axial position.
Use your answers from Problem 2.48 to complete the table showing correlations between cis,trans and axial,equatorial for disubstituted derivatives of cyclohexane. Draw the alternative chair conformations for the cis and trans isomers of 1,2-dimethylcyclohexane, 1,3-dimethylcyclohexane, 1,4-dimethylcyclohexane. (a) Indicate by a label whether each methyl group is axial or equatorial.
Following is a planar hexagon representation of L-fucose, a sugar component of the determinants of the A, B, O blood group typing. For more on this system of blood typing, see Chemical Connections: A, B, AB, and O Blood Group Substances in Chapter 25. (a) Draw the alternative chair conformations of L-fucose. (b) Which of them is more stable? Explain.
Consider the cyclohexane below. CH3 Part 1 of 3 H₂C H₂C H₂C 6 ... 4 CH3 Use the cyclohexane conformation drawing tool and guide points to draw the given cyclohexane. Be sure to draw each substituent in the same positi number on the chair conformation. H₂C H₁₂C CH3 HC CH₂3 Use the cyclohexane conformation drawing tool and guide points to draw the result of the ring inversion of the original chair conformation from Part 1.
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ollowing are the alternative chair conformations for trans-1,2-dimethylcyclohexane. Q.) Estimate the difference in free energy between these two conformations.
CYCLOHEXANE 2D REPRESENTATION Cyclohexane Chair by stereoaisier H H H. „CH2. H CH H. H H V STAGGERED O ECLIPSED O 1,3-DIAXIAL INTERACTION CHAIR BOAT CHAIR In which conformation are the hydrogen atoms farthest apart? Which is the preferred conformation? Give reasons for your answer. Which is the eclipsed conformation?
for the following substituted cyclohexane, draw both chair conformations. Using rules of cyclohexane substituent stability and known strain values, verify which is the more stable of the two HO H₂Nim b H
4. Draw the most stable chair conformation of the following disubstituted cyclohexane. Draw carefully positioned intersecting arcs to denote all sources of steric strain for this conformation. CH3 CH3