10. Which ONE of the following compounds contains a chiral center?A) 2,2-dichlorobutaneB) 1,2-dichlorobutaneC) 1,4-dichlorobutaneD) 2,2-dichloropentaneE) 1,3,5-trichloropentane

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Answered: 10. Which ONE of the following…

Chemistry: Matter and Change

1st Edition

ISBN:9780078746376

Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Chapter21: Hydrocarbons

Section: Chapter Questions

Problem 94A

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Which of the following molecules can have enantiomers? Identify any chiral carbon atoms. a. b. c.
11. Which carbon atom(s) is/are chiral? How many stereoisomers are possible? OH
Which of the following compounds would be optically active? For those that are draw the skeletal structure and indicate the chiral center(s)with an asterisk. a. CH3CH(NH2)COOH b. CH3CH2CH2CH3 c. CH3CH2CHClCH3
18. How many chiral carbon atoms does chlorocyclohexane have? a) Zero b) One c) Two d) More than two
Draw all the optical isomers of 3-methylhexan-2-ol – you should be able to draw four (two pairs of enantiomers (A+B and C+D) – identify the pairs of enantiomers. Draw a circle around the 2S, 3R isomer.
Draw structures of the following molecules.
18. Consider the following two compounds: CH3CH2CH2CH2CH3 and (CH3)2CHCH2CH3 Which statement below is INCORRECT? A) CH3CH₂CH₂CH₂CH3 has the higher boiling point. B) Greater surface area leads to more intermolecular attraction which results in a higher boiling point. C) (CH3)2CHCH2CH3 has the higher boiling point D) As the degree of branching increases, the surface area of the molecule decreases and the potential for intermolecular attraction via London forces decreases.
For each of the following compounds,determine whether each is optically active. For optically active compounds, identify the chiral carbon: ethane, 2-chloro-2-methylbutane, CH3CH(NH2)COOH, CH3CH2CHClCH3and CH3CH2CH2CH3. And for non-optical active compounds, just provide the structure of the compound
2. Draw all of the stereoisomers of dichlorocyclopentane. Use dashed lines and wedges (Hint: you should have 7 different/unique structures)
Draw the structure for 2-bromo-2-chloro-3,4-dimethylhexane and state which if any carbons are chiral using the carbon number. Example: C1.
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There are 17 possible alkene isomers with the formula C6H12. Draw structures of the five isomers in which the longest chain has six carbon atoms, and give the name of each. Are any of these isomers chiral? (There are also eight isomers in which the longest chain has five carbon atoms, and four isomers in which the longest chain has four carbon atoms. How many can you find?)

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10. Which ONE of the following compounds contains a chiral center? A) 2,2-dichlorobutane B) 1,2-dichlorobutane C) 1,4-dichlorobutane D) 2,2-dichloropentane E) 1,3,5-trichloropentane