An equimolar amount of the three compounds below are mixed and treated with base followedby an acidic workup.1. 1 eq. (BUOKof+NC.H.OMe2. acidic workupWhich molecule acts as the nucleophile?Enter your answer hereProvide a valid explanation... Why did you choose what you chose and not something else?Enter your answer hereWhich molecule acts as the electrophile?Enter your answer hereProvide a valid explanation... Why did you choose what you chose and not something else?Enter your answer here

step 1 3-oxobutanenitrile - act as the nucleophile.

Answered: An equimolar amount of the three…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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(8) Which nucleophile in cach pair will react faster in SN2 reactions? Circle one choice in cach pair. IN GENERAL, the stronger base - more reactive nucleophile. EXCEPTION: When comparing neutral species in the same column of the periodic table, the LARGER species is the most reactive (more polarizable). HO or HS cr or PH; ASH, or NH, NH, or Na* NH;
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3) Design a reasonable synthesis for the following transformation. = trort + B.
I. For each molecule below 1) Show the radical cation that would form, including all non-bonding electrons, if the molecule were subjected to electron impact mass spectrometry 2) Show the electron pushing mechanism for a. an a-cleavage reaction of the radical cation drawn in part 1) for molecule A. b. a McLafferty rearrangement of the radical cation drawn in part 1) for molecule B. 3) Show both products of the mechanism in part 2) A B Jön OH Electron Impact Mass Spec Electron Impact Mass Spec
Topic #2: Arrange the following in order of decreasing reactivity to nucleophilic acyl substitution:ester, amide, acid anhydride.Explain your logic. You should include :1) the order in decreasing reactivity2) Discussion of these factors as they pertain to the above compounds: carbonyl carbon delta +, resonance, steric effects, and leaving group
[References] How would you synthesize the following compounds from butanenitrile using reagents from the table? Use letters from the table to list reagents in the order used (first at the left). Example: ab Reagents 1. NaOH / H2O 2. H3O* SOCI2 1. NABH4 a e i 2. H3O* 1. ВНз / THF 2. НаО2/ NaOН b f 1. LIAIH4 1. CH3CH2MGBR / dry ether 2. H30* j 2. H3O* 1. (CH3)2CHMGB / dry ether 2. H30* PBR3 g NaCN k d Dess-Martin h CrO3 / H30* conc. HCI periodinane in CH2CI2 a) 2-Methyl-3-hexanone b) Pentanoic acid
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Rank for OChem
The triphenylmethyl radical is an unusual persistent radical present in solution in equilibrium with its dimer. For 70 years the dimer was thought to be hexaphenylethane, but in 1970, NMR data showed it to be A. a.Why is the triphenylmethyl radical more stable than most other radicals? b.Use curved arrow notation to show how two triphenylmethyl radicals dimerize to form A. c.Propose a reason for the formation of A rather than hexaphenylethane. d.How could 1H and 13C NMR spectroscopy be used to distinguish between hexaphenylethane and A?
b. 2. Propose a multi-step synthesis for the following molecules. a. Br O₂N CH3 Br NO₂ CH₂CH3
C341 Chapters (Acid-base chemistry) 9.) Acid-base equilibrium. For each reaction, perform the following tasks: a.) Complete the following reactions using the appropriate curved arrows to demonstrate the flow of electrons pairs in each potential reaction. b.) Indicate if the reaction lies to the right or the left (circle the correct arrow direction). c.) Calculate an approximate Ken for each reaction. d.) Write the pKa values under each acid, so we can evaluate your progress better and award partial credit. d.) Finally, label the acid (A), base (B), conjugate acid (CA) and base (CB) correctly based on the direction you decided. Keq = Direction: OH eg HO Keq = Direction: Keq = Direction: LOH OH ONa لها LIⒸ CHgLi Page 5 of 7

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