Problem 14.22 Vibrational frequencies are sensitive to isotopic replacement. The O-H stretching frequency is near 3600 cm, but that of O-D is about 2630 cm ¹. Which are closer in energy, two adjacent O-H or two adjacent O-D vibrational states? for

Physical Chemistry
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Author:Ball, David W. (david Warren), BAER, Tomas
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Chapter15: Introduction To Electronic Spectroscopy And Structure
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Organic Chemistry 2 - 14.22

Problem 14.22
Vibrational frequencies are sensitive to isotopic replacement. The O-H stretching frequency
is near 3600 cm, but that of O-D is about 2630 cm ¹. Which are closer in energy, two
adjacent O-H or two adjacent O-D vibrational states?
for
Transcribed Image Text:Problem 14.22 Vibrational frequencies are sensitive to isotopic replacement. The O-H stretching frequency is near 3600 cm, but that of O-D is about 2630 cm ¹. Which are closer in energy, two adjacent O-H or two adjacent O-D vibrational states? for
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