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CH3. H3C, H3C" HH CH3 Ring-flip H3C H3C H- -CI A B (A) A=1.0 kJ/mol; B=11.4 kJ/mol; difference = 10.4 kJ/mol (B) A=2.0 kJ/mol; B=22.8 kJ/mol; difference = 20.8 kJ/mol (C) A=3.0 kJ/mol; B=22.8 kJ/mol; difference = 19.8 kJ/mol (D) A=1.0 kJ/mol; B=22.8 kJ/mol; difference = 21.8 kJ/mol %3D (E) A=2.0 kJ/mol; B=11.4 kJ/mol; difference = 9.4 kJ/mol

CH3. H3C, H3C" HH CH3 Ring-flip H3C H3C H- -CI A B (A) A=1.0 kJ/mol; B=11.4 kJ/mol; difference = 10.4 kJ/mol (B) A=2.0 kJ/mol; B=22.8 kJ/mol; difference = 20.8 kJ/mol (C) A=3.0 kJ/mol; B=22.8 kJ/mol; difference = 19.8 kJ/mol (D) A=1.0 kJ/mol; B=22.8 kJ/mol; difference = 21.8 kJ/mol %3D (E) A=2.0 kJ/mol; B=11.4 kJ/mol; difference = 9.4 kJ/mol

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please answer this NEATLY, COMPLETELY, and CORRECTLY for an UPVOTE.

Long and detailed explanations are not needed. Keep it short, brief, and direct because I only need the answers as soon as possible.

Calculate the total strain energy in each of the two chair conformations of cis-1-tert-butyl-4-chlorocyclohexane. By how much energy is the more stable conformation favored (this is the difference in energy between the two conformations)?

NOTE: The strain energy for one H,Cl interaction is 1.0 kJ/mol while for H,-C(CH3)3 (t-butyl) is 11.4 kJ/mol.

CH3. H3C, H3C" HH CH3 Ring-flip H3C H3C H- -CI A B (A) A=1.0 kJ/mol; B=11.4 kJ/mol; difference = 10.4 kJ/mol (B) A=2.0 kJ/mol; B=22.8 kJ/mol; difference = 20.8 kJ/mol (C) A=3.0 kJ/mol; B=22.8 kJ/mol; difference = 19.8 kJ/mol (D) A=1.0 kJ/mol; B=22.8 kJ/mol; difference = 21.8 kJ/mol %3D (E) A=2.0 kJ/mol; B=11.4 kJ/mol; difference = 9.4 kJ/mol
Transcribed Image Text:CH3. H3C, H3C" HH CH3 Ring-flip H3C H3C H- -CI A B (A) A=1.0 kJ/mol; B=11.4 kJ/mol; difference = 10.4 kJ/mol (B) A=2.0 kJ/mol; B=22.8 kJ/mol; difference = 20.8 kJ/mol (C) A=3.0 kJ/mol; B=22.8 kJ/mol; difference = 19.8 kJ/mol (D) A=1.0 kJ/mol; B=22.8 kJ/mol; difference = 21.8 kJ/mol %3D (E) A=2.0 kJ/mol; B=11.4 kJ/mol; difference = 9.4 kJ/mol
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