Q2. Answer any TWO of the following parts: (a) Draw the two main conformations that exist for cyclohexane. Explain clearly why one conformer is more stable than the other. Using cis-1-ethyl-3-methylcyclohexane, as an example, explain how ring flipping occurs. Draw both conformers of cis-1-ethyl-3-methylcyclohexane and explain clearly which one predominates. (b) What is polarimetry? The specific rotation of (R)-carvone is - 61°. A chemist prepared a 750 mg mixture of (R)-carvone and its enantiomer in 10 ml of ethanol and placed the solution in a 10 cm polarimeter cell. The observed rotation was -4.125° Calculate the specific rotation for the above mixture. What is meant by enantiomeric excess? Then determine the % enantiomeric excess (% ee) in the mixture. (i) (ii) (iii) What % of the mixture is (R)-carvone and (S)-carvone?
Q2. Answer any TWO of the following parts: (a) Draw the two main conformations that exist for cyclohexane. Explain clearly why one conformer is more stable than the other. Using cis-1-ethyl-3-methylcyclohexane, as an example, explain how ring flipping occurs. Draw both conformers of cis-1-ethyl-3-methylcyclohexane and explain clearly which one predominates. (b) What is polarimetry? The specific rotation of (R)-carvone is - 61°. A chemist prepared a 750 mg mixture of (R)-carvone and its enantiomer in 10 ml of ethanol and placed the solution in a 10 cm polarimeter cell. The observed rotation was -4.125° Calculate the specific rotation for the above mixture. What is meant by enantiomeric excess? Then determine the % enantiomeric excess (% ee) in the mixture. (i) (ii) (iii) What % of the mixture is (R)-carvone and (S)-carvone?
Chemistry
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Chapter1: Chemical Foundations
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
Transcribed Image Text:Q2.
Answer any TWO of the following parts:
(a) Draw the two main conformations that exist for cyclohexane. Explain clearly
why one conformer is more stable than the other.
Using cis-1-ethyl-3-methylcyclohexane, as an example, explain how ring
flipping occurs.
Draw both conformers of cis-1-ethyl-3-methylcyclohexane and explain clearly
which one predominates.
(b) What is polarimetry? The specific rotation of (R)-carvone is - 61°. A chemist
prepared a 750 mg mixture of (R)-carvone and its enantiomer in 10 ml of
ethanol and placed the solution in a 10 cm polarimeter cell. The observed
rotation was -4.125°
Calculate the specific rotation for the above mixture.
What is meant by enantiomeric excess? Then determine the %
enantiomeric excess (% ee) in the mixture.
(i)
(ii)
(iii)
What % of the mixture is (R)-carvone and (S)-carvone?
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