Carbon disulfide and oxygen react to form carbon dioxide and sulfur dioxide, like this: CS₂(g) +30₂(g) → CO₂(g) +2SO₂(g) Suppose a mixture of CS2, O₂, CO2 and SO₂ has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation Some CS₂ is removed. Some CO₂ is added. change in composition The pressure of O₂ will The pressure of CO₂ will The pressure of CS₂ will The pressure of O₂ will ? ? ? ? e e 0 shift in equilibrium X Oto the right O to the left O (none) Oto the right Oto the left O (none) 3

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**Carbon Disulfide and Oxygen Reaction:**

Carbon disulfide and oxygen react to form carbon dioxide and sulfur dioxide, as shown in the reaction below:

\[ \text{CS}_2(g) + 3\text{O}_2(g) \rightarrow \text{CO}_2(g) + 2\text{SO}_2(g) \]

**Equilibrium Analysis:**

Suppose a mixture of CS₂, O₂, CO₂, and SO₂ has reached equilibrium in a closed reaction vessel. Predict the effects of specific perturbations on the composition of the mixture in the vessel. Also, determine the direction in which the equilibrium shifts.

**Perturbation and Equilibrium Shift Table:**

| Perturbation         | Change in Composition                | Shift in Equilibrium |
|----------------------|--------------------------------------|----------------------|
| Some CS₂ is removed. | The pressure of O₂ will ______      | ☐ to the right       |
|                      | The pressure of CO₂ will ______     | ☐ to the left        |
|                      |                                      | ☐ (none)             |
|                      |                                      |                      |
| Some CO₂ is added.   | The pressure of CS₂ will ______     | ☐ to the right       |
|                      | The pressure of O₂ will ______      | ☐ to the left        |
|                      |                                      | ☐ (none)             |

This table is used to analyze how changes in the concentration of substances affect the equilibrium position according to Le Chatelier's Principle. Fill in the blanks and select the appropriate shift in equilibrium direction for each scenario.
Transcribed Image Text:**Carbon Disulfide and Oxygen Reaction:** Carbon disulfide and oxygen react to form carbon dioxide and sulfur dioxide, as shown in the reaction below: \[ \text{CS}_2(g) + 3\text{O}_2(g) \rightarrow \text{CO}_2(g) + 2\text{SO}_2(g) \] **Equilibrium Analysis:** Suppose a mixture of CS₂, O₂, CO₂, and SO₂ has reached equilibrium in a closed reaction vessel. Predict the effects of specific perturbations on the composition of the mixture in the vessel. Also, determine the direction in which the equilibrium shifts. **Perturbation and Equilibrium Shift Table:** | Perturbation | Change in Composition | Shift in Equilibrium | |----------------------|--------------------------------------|----------------------| | Some CS₂ is removed. | The pressure of O₂ will ______ | ☐ to the right | | | The pressure of CO₂ will ______ | ☐ to the left | | | | ☐ (none) | | | | | | Some CO₂ is added. | The pressure of CS₂ will ______ | ☐ to the right | | | The pressure of O₂ will ______ | ☐ to the left | | | | ☐ (none) | This table is used to analyze how changes in the concentration of substances affect the equilibrium position according to Le Chatelier's Principle. Fill in the blanks and select the appropriate shift in equilibrium direction for each scenario.
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