Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The height or area under each HNMR peak is proportional to the relative number of protons associated with a given sight. Use the integrals below to determine the number of protons associated with signals a-c

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### Nuclear Magnetic Resonance (NMR) Spectrum Analysis
#### Chemical Analysis of C₉H₁₀O₂
The following NMR spectrum represents the chemical shifts of a species with the molecular formula C₉H₁₀O₂. The spectrum is detailed along a PPM (parts per million) scale, ranging from 0 to 9 PPM. The data includes three primary peaks labeled 'a,' 'b,' and 'c,' along with their corresponding areas in units.
### Spectrum Breakdown
##### Peaks and Areas:
1. **Peak 'a'**
- **PPM Range:** Approximately 2 PPM
- **Area:** 33 Units
2. **Peak 'b'**
- **PPM Range:** Approximately 5 PPM
- **Area:** 23 Units
3. **Peak 'c'**
- **PPM Range:** Approximately 7 PPM
- **Area:** 54 Units
### Graph Description:
- **X-axis (PPM):** This axis represents the chemical shift in parts per million (PPM), a standard unit for NMR spectra.
- **Y-axis:** Intensity of the peaks although not specifically labeled, is understood to represent the relative number of protons corresponding to each chemical environment.
- **Molecular Formula:** The molecular formula C₉H₁₀O₂ is provided at the top left of the spectrum, indicating the composition of the analyzed compound.
- **Peak Identification:** Each peak corresponds to a distinct chemical environment within the molecule:
- Peak 'c' at ~7 PPM (54 units) often correlates with protons in an aromatic ring.
- Peak 'b' at ~5 PPM (23 units) might suggest protons in a vinyl or aldehyde group environment.
- Peak 'a' at ~2 PPM (33 units) typically suggests protons in a methyl group adjacent to a carbonyl group.
### Educational Notes:
- The areas under the peaks (integrals) are directly proportional to the number of hydrogen atoms represented by that peak.
- The chemical shifts can indicate the types of hydrogen atoms present in different chemical environments.
- Understanding and interpreting NMR spectra are crucial for chemists in identifying the structure of organic compounds.
### Example
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