C Write a mechanism for the step shown below, using curved arrows to show electron redistribution. Arrow-pushing Instructions X H HỘ LCH,CH3 H—ỊCH, CH3 H-OCH₂CH3 Submit + OH
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
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![**Instructions for Arrow-Pushing in Chemical Reactions**
**Task:** Write a mechanism for the step shown below, using curved arrows to show electron redistribution.
**Arrow-Pushing Instructions:**
- The curved arrows are used to indicate the movement of electrons during the reaction mechanism.
**Diagram Details:**
1. **Reactants:**
- The left structure is a five-membered ring with a hydroxyl group (OH) and an ethoxy group (OCH₂CH₃) attached. There's also a positive charge indicated on the ring oxygen.
2. **Reaction Mechanism:**
- Curved arrows should be drawn to show the electron flow:
- One arrow starts from the lone pair of electrons on the oxygen of the hydroxyl group and points towards the bond between the oxygen and carbon.
- Another arrow shows the departure of the bond electrons of the ethoxy group.
3. **Products:**
- The right structure indicates the ethoxonium ion with a positive charge on the oxygen.
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This mechanism illustrates how electron movement and bond rearrangement occur during this transformation in an organic reaction.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9b558fbd-26e6-4818-8b53-7c480a77ba3e%2F724e04da-f89d-4813-898b-030991316ec0%2Fuwjp7rm_processed.jpeg&w=3840&q=75)
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Acetals are the products formed by the reaction between aldehyde or ketone with alcohol. Acetals are the structure having two seperate oxygen are connected to central carbon. And this oxygen further connected to two same or different alkyl groups.
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