Butenes, such as 1-butene undergo isomerization in the presence of a catalyst to form isobutene according to the equation: 1-butene isobutene The equilibria were studied in the gas phase at high temperatures (Petroleum Chemistry. 2001, 41, 144-148). The equilibrium constant for the isomerization of 1- butene to isobutene at 555 °C is K- 0.80. A misxture of 1-butene (P= 1.05 bar) and isobutene (P=2.58 bar) were placed in a vessel at 555 °C and were allowed to come to equilibrium.

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Butenes, such as 1-butene undergo isomerization in the presence of a catalyst to
form isobutene according to the equation:
1-butene
isobutene
The equilibria were studied in the gas phase at high temperatures (Petroleum
Chemistry. 2001. 41, 144-148). The equilibrium constant for the isomerization of 1-
butene to isobutene at 555 °C is K= 0.89.
A mixture of 1-butene (P= 1.65 bar) and isobutene (P = 2.58 bar) were placed in a
vessel at 555 °C and were allowed to come to equilibrium.
Transcribed Image Text:Butenes, such as 1-butene undergo isomerization in the presence of a catalyst to form isobutene according to the equation: 1-butene isobutene The equilibria were studied in the gas phase at high temperatures (Petroleum Chemistry. 2001. 41, 144-148). The equilibrium constant for the isomerization of 1- butene to isobutene at 555 °C is K= 0.89. A mixture of 1-butene (P= 1.65 bar) and isobutene (P = 2.58 bar) were placed in a vessel at 555 °C and were allowed to come to equilibrium.
The reaction will proceed toward 1-butene to reach equilibrium. Determine the partial pressures of 1-butene and isobutene.
O Pi-butene 2.4 bar. Pisobutene
= 2.7 bar
O Pbutene
= 2.8 bar. Pisobutene
= 2.5 bar
O P,
1-butene
= 2.7 bar. P.
isobutene
= 2.4 bar
1-butene
= 2.2 bar, P
isobutene
= 2.0 bar
Transcribed Image Text:The reaction will proceed toward 1-butene to reach equilibrium. Determine the partial pressures of 1-butene and isobutene. O Pi-butene 2.4 bar. Pisobutene = 2.7 bar O Pbutene = 2.8 bar. Pisobutene = 2.5 bar O P, 1-butene = 2.7 bar. P. isobutene = 2.4 bar 1-butene = 2.2 bar, P isobutene = 2.0 bar
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