BrCH4(Review section 7.5.)Br(racemic)

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Answered: Br CH4 (Review section 7.5.) Br…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter19: Transitition Metals, Coordination Chemistry And Metallurgy

Section: Chapter Questions

Problem 19.41QE

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b) A student finds two bottles of colourless liquid containing the same molecule (shown below), but one bottle (A) is labelled "racemic" and the other (B) is labelled "enantiopure". i) Describe what is meant by "racemic". In the context of Bottle A, what does that say about the actual contents of the bottle? ii) Conversely, what do you think is meant by “enantiopure" in the context of Bottle B? A ОН В ОН 1-phenylethanol 1-phenylethanol racemic enantiopure
4. What is the meaning of: [a] s-cis diene [b] stereo dot [c] bridgehead position
1. Why regioselectivity? 2. Why stereoselectivity? 3. What are the changes in the oxidation state?
(a) Identify the missing major products A and B from the reactions below. ( b) For the catalyst used for each transformation, draw the structure and state the formal electron count and oxidation state (showing your workings)
Draw the structure of the following compounds and indicate the formal oxidation state and the number of electrons in the valence shell of the metal. Predict whether each of these compounds may be stable enough to be characterized under normal ambient conditions. (i) [Rh(n2-C2H4)(PPh3)2Cl] (ii) [(n5-C5H5)2Ti(CO)2] (iii) [(n5-C5H5)Mo(CO)2(n3-C3H5)] (iv) [Fe(n6-C6H6)2] Can you please explain how to get these answers in detail, im more interetsed in understanding it rather than having answers.
Give the resonance structure of [CH3C(OCH3)2]+
3. For medicinal substances: sodium chloride, formaldehyde solution, ascorbic acid - the general reaction of authenticity is the reaction with?A) Iron (III) chlorideB) Silver nitrateC) ChloramineD) Sodium nitriteE) Potassium permanganate
structures to illustrate your answers 2. The tropylium ion is colorless, whereas the tropenide ion is dark blue. Tropylium ion Tropenide ion
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When trans-[CrCl2(NH3)4] * is reacted with one equivalent Nal, trans- and cis- [CrCl(I) (NH3)4] * are obtained. However, only trans-[COCI(I)(NH3)4] * forms when Nal is reacted with the trans-[CoCl2(NH3)4] * .
what is the IUPAC name of {Pt(Cl) (H) (Et3P)2 } ?
1. What is the valence electron count and oxidation state for [1,3,5-C6H3(CH3)3]Mo(CO)3?2. Do you expect the C-C bond lengths in the arene ring to be longer or shorter once bound to Mo?3. An alternative preparation can use high intensity light, how does irradiation of Mo(CO)6 improve the reaction?

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Br CH4 (Review section 7.5.) Br (racemic)