Below, depicts the electron flow process for the synthetic schemes. This should include the prediction of significant and by-products through electronic and structural impacts. The mechanism for pushing the arrow must be shown. SYNTHESIS OF TEREPHTALIC ACID AICI3 CH3CI HCI + toluene Scheme 1. Formation of Toluene using Friedel Craft Alkylation Br2 + FeBr3 Br Br toluene o-Bromotoluene p-Bromotoluene Scheme 2. Bromination of Toluene using Br:/FeBr3 Mg Br Mg HO. Br ether p-Bromotoluene phenylmagnesium bromide acetic acid Scheme 3. Bromo 1 methyl benzene forms Grignard reagent upon reacting magnesium KMN04 HO он HO acetic acid Terephthalic acid Scheme 4. Bromo 1 methyl benzoic acid umdergo oxidation in presence of potassium permanganate to form COOH and we get the desired acid (Terephthalic acid) O=

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Chapter1: Chemical Foundations
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Please indicate an arrow push for each reaction.

 

Below, depicts the electron flow process for the synthetic schemes. This should include the
prediction of significant and by-products through electronic and structural impacts. The mechanism
for pushing the arrow must be shown.
SYNTHESIS OF TEREPHTALIC ACID
AICI3
HCI
CH3CI
+
+
toluene
Scheme 1. Formation of Toluene using Friedel Craft Alkylation
Br2
+
FeBr3
Br
Br
toluene
o-Bromotoluene
p-Bromotoluene
Scheme 2. Bromination of Toluene using Br:/FeBr3
Mg
Br
Mg
HO.
Br
ether
p-Bromotoluene
phenylmagnesium bromide
acetic acid
Scheme 3. Bromo 1 methyl benzene forms Grignard reagent upon reacting
magnesium
KMN04
но
HO,
acetic acid
Terephthalic acid
Scheme 4. Bromo 1 methyl benzoic acid undergo oxidation in presence of potassium
permanganate to form COOH and we get the desired acid (Terephthalic acid)
Transcribed Image Text:Below, depicts the electron flow process for the synthetic schemes. This should include the prediction of significant and by-products through electronic and structural impacts. The mechanism for pushing the arrow must be shown. SYNTHESIS OF TEREPHTALIC ACID AICI3 HCI CH3CI + + toluene Scheme 1. Formation of Toluene using Friedel Craft Alkylation Br2 + FeBr3 Br Br toluene o-Bromotoluene p-Bromotoluene Scheme 2. Bromination of Toluene using Br:/FeBr3 Mg Br Mg HO. Br ether p-Bromotoluene phenylmagnesium bromide acetic acid Scheme 3. Bromo 1 methyl benzene forms Grignard reagent upon reacting magnesium KMN04 но HO, acetic acid Terephthalic acid Scheme 4. Bromo 1 methyl benzoic acid undergo oxidation in presence of potassium permanganate to form COOH and we get the desired acid (Terephthalic acid)
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