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NaNH2 `NH2 CI i) NaNH2 NH2 Br ii)

NaNH2 `NH2 CI i) NaNH2 NH2 Br ii)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Circle the reaction in the pair that will undergo reaction more readily.
The image illustrates two chemical reactions involving aromatic substitution using sodium amide (NaNH₂) as a reagent. i) The first reaction shows benzyl chloride (Cl attached to a benzene ring via a methylene group) reacting with NaNH₂. The chloride group (Cl) is replaced by an amino group (NH₂), resulting in benzylamine. Reactants: - Benzyl chloride (C₆H₅CH₂Cl) - Sodium amide (NaNH₂) Product: - Benzylamine (C₆H₅CH₂NH₂) ii) The second reaction displays benzyl bromide (Br attached to a benzene ring via a methylene group) reacting with NaNH₂. Similarly, the bromide group (Br) is replaced by an amino group (NH₂), producing benzylamine. Reactants: - Benzyl bromide (C₆H₅CH₂Br) - Sodium amide (NaNH₂) Product: - Benzylamine (C₆H₅CH₂NH₂) In both reactions, the aromatic ring remains unchanged, and the substitution occurs at the carbon attached to the halogen (Cl or Br), leading to the formation of an amine.
Transcribed Image Text:The image illustrates two chemical reactions involving aromatic substitution using sodium amide (NaNH₂) as a reagent. i) The first reaction shows benzyl chloride (Cl attached to a benzene ring via a methylene group) reacting with NaNH₂. The chloride group (Cl) is replaced by an amino group (NH₂), resulting in benzylamine. Reactants: - Benzyl chloride (C₆H₅CH₂Cl) - Sodium amide (NaNH₂) Product: - Benzylamine (C₆H₅CH₂NH₂) ii) The second reaction displays benzyl bromide (Br attached to a benzene ring via a methylene group) reacting with NaNH₂. Similarly, the bromide group (Br) is replaced by an amino group (NH₂), producing benzylamine. Reactants: - Benzyl bromide (C₆H₅CH₂Br) - Sodium amide (NaNH₂) Product: - Benzylamine (C₆H₅CH₂NH₂) In both reactions, the aromatic ring remains unchanged, and the substitution occurs at the carbon attached to the halogen (Cl or Br), leading to the formation of an amine.
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