b. е. a. from HO "Br from from C3H12 "O., from 3. Provide mechanisms for the following reactions. Show all key intermediates and indicate electrom flow using arrows.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Main question is in the first picture. Please answer both questions.
OH
b.
a.
from
HO-
"Br
from
from C3H12
from
3. Provide mechanisms for the following reactions. Show all key intermediates and indicate electron
flow using arrows.
HBr
Transcribed Image Text:OH b. a. from HO- "Br from from C3H12 from 3. Provide mechanisms for the following reactions. Show all key intermediates and indicate electron flow using arrows. HBr
g.
+37 other
minor
5-epi-aristolochene
products
depending
on the
enzymatic
systems
involved
ÓPP
hint: -OPP is an -OPO3PO3 group that
can undergo heterolytic cleavage to form
a resonance stabilized carbocation
premnaspirodiene
This is a challenging problem - lots of steps. It may
help if you know that this compound with the indicated
red bond being the only C-C bond formed is the first
intermediate formed from the allylic carbocation above
though even that is not a whole lot of help
Transcribed Image Text:g. +37 other minor 5-epi-aristolochene products depending on the enzymatic systems involved ÓPP hint: -OPP is an -OPO3PO3 group that can undergo heterolytic cleavage to form a resonance stabilized carbocation premnaspirodiene This is a challenging problem - lots of steps. It may help if you know that this compound with the indicated red bond being the only C-C bond formed is the first intermediate formed from the allylic carbocation above though even that is not a whole lot of help
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