B. A reaction (A + B →C) was catalyzed by a solid catalyst with dual surface sites (S1 and S2) via a reaction mechanism proposed in below: Adsorption of A: A + S₁ ← Adsorption of B: B+S₂ A. S₁ B-S2 Surface reaction: A S₁+B S2C+S₁ + S₂ KA, KA KB, KB krxn where k and K represent forward rate constant and equilibrium constant, respectively. Assuming the surface reaction is the rate-determining step, derive the expression for the formation rate of C.

B. A reaction (A + B →C) was catalyzed by a solid catalyst with dual surface sites (S1 and S2) via a reaction mechanism proposed in below: Adsorption of A: A + S₁ ← Adsorption of B: B+S₂ A. S₁ B-S2 Surface reaction: A S₁+B S2C+S₁ + S₂ KA, KA KB, KB krxn where k and K represent forward rate constant and equilibrium constant, respectively. Assuming the surface reaction is the rate-determining step, derive the expression for the formation rate of C.

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.49PAE: The rate of photodecomposition of the herbicide piclo- ram in aqueous systems was determined by...

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