Average Bond Enthalpies (kJ/mol) TABLE 8.3 Single Bonds C-H 413 N-H 391 О—н 463 F-F 155 348 N-N 163 0-0 146 CI-F 293 201 0-F 190 253 C-0 358 N-F 272 0-CI 203 Cl-CI 242 C-F 485 200 0-I 234 N-CI 243 C-CI 328 N-Br Br-F 237 C-Br 276 S-H 339 Br-CI 218 C-I 240 Н-Н 436 S-F 327 Br-Br 193 C-S 259 Н—F 567 S-CI 253 Н—СІ 431 S-Br 218 I-CI 208 Si-H 323 Н—Br 366 S-S 266 I-Br 175 Si-Si 226 Н-I 299 I-I 151 Si-C 301 Si-O 368 Si-CI 464 Multiple Bonds 495 614 N=N 418 0=0 839 N=N 941 615 607 523 C=N 891 S=S 418 799 1072 (а) Br Br Br-C-H+ Cl–CI→ Br-Ċ-Cl+H- Br Br (b) H-S—ҫ-ҫ—s—H+2H—Br H H нн Br—C—с—Вr + 2 H—S—H нн (c) нн H Н-N—N-H + CІ—CІ — 2 Н-N—CI I-U-I

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Using Table 8.3, estimate ΔH for the following gas-phase
reactions:

Average Bond Enthalpies (kJ/mol)
TABLE 8.3
Single Bonds
C-H
413
N-H
391
О—н
463
F-F
155
348
N-N
163
0-0
146
CI-F
293
201
0-F
190
253
C-0
358
N-F
272
0-CI
203
Cl-CI
242
C-F
485
200
0-I
234
N-CI
243
C-CI
328
N-Br
Br-F
237
C-Br
276
S-H
339
Br-CI
218
C-I
240
Н-Н
436
S-F
327
Br-Br
193
C-S
259
Н—F
567
S-CI
253
Н—СІ
431
S-Br
218
I-CI
208
Si-H
323
Н—Br
366
S-S
266
I-Br
175
Si-Si
226
Н-I
299
I-I
151
Si-C
301
Si-O
368
Si-CI
464
Multiple Bonds
495
614
N=N
418
0=0
839
N=N
941
615
607
523
C=N
891
S=S
418
799
1072
Transcribed Image Text:Average Bond Enthalpies (kJ/mol) TABLE 8.3 Single Bonds C-H 413 N-H 391 О—н 463 F-F 155 348 N-N 163 0-0 146 CI-F 293 201 0-F 190 253 C-0 358 N-F 272 0-CI 203 Cl-CI 242 C-F 485 200 0-I 234 N-CI 243 C-CI 328 N-Br Br-F 237 C-Br 276 S-H 339 Br-CI 218 C-I 240 Н-Н 436 S-F 327 Br-Br 193 C-S 259 Н—F 567 S-CI 253 Н—СІ 431 S-Br 218 I-CI 208 Si-H 323 Н—Br 366 S-S 266 I-Br 175 Si-Si 226 Н-I 299 I-I 151 Si-C 301 Si-O 368 Si-CI 464 Multiple Bonds 495 614 N=N 418 0=0 839 N=N 941 615 607 523 C=N 891 S=S 418 799 1072
(а) Br
Br
Br-C-H+ Cl–CI→ Br-Ċ-Cl+H-
Br
Br
(b)
H-S—ҫ-ҫ—s—H+2H—Br
H H
нн
Br—C—с—Вr + 2 H—S—H
нн
(c)
нн
H
Н-N—N-H + CІ—CІ — 2 Н-N—CI
I-U-I
Transcribed Image Text:(а) Br Br Br-C-H+ Cl–CI→ Br-Ċ-Cl+H- Br Br (b) H-S—ҫ-ҫ—s—H+2H—Br H H нн Br—C—с—Вr + 2 H—S—H нн (c) нн H Н-N—N-H + CІ—CІ — 2 Н-N—CI I-U-I
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