At 90 °C the vapour pressure of toluene is 400 mmHg and that of o-xylene is 150 mmHg. (i) What is the composition of a liquid mixture that will boil at 90 °C when the pressure is 0.5 atm? (ii) What is the composition of the vapour produced? (Common sense suggests that the vapour should be richer in the more volatile component. We want to confirm this!)

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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At 90 °C the vapour pressure of toluene is 400 mmHg and that of o-xylene is 150 mmHg.
(i) What is the composition of a liquid mixture that will boil at 90 °C when the pressure is
0.5 atm? (ii) What is the composition of the vapour produced? (Common sense suggests
that the vapour should be richer in the more volatile component. We want to confirm
this!)
Transcribed Image Text:T2 At 90 °C the vapour pressure of toluene is 400 mmHg and that of o-xylene is 150 mmHg. (i) What is the composition of a liquid mixture that will boil at 90 °C when the pressure is 0.5 atm? (ii) What is the composition of the vapour produced? (Common sense suggests that the vapour should be richer in the more volatile component. We want to confirm this!)
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