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- Please give the main substitution product for each of the following reactions, and indicate the dominant mechanism: (a) 1-bromopropane + NaOCH3 → (b) 3-bromo-3-methylpentane + NaOC2H5 →Which represents an efficient synthetic route to go from an alkane to an alkene? O elimination with NaNH2, followed by a water workup O anti-Markovnikov hydrohalogenation, followed by elimination O radical bromination, followed by elimination O hydration, followed by elimination O hydration, followed by ozonolysis of the double bondProvide the structure(s) of the expected major organic product of the reaction shown. 1) Disiamylborane 2) H₂O₂, NaOH OI O II ||| O IV OV CH3CH₂C(CH3)2C=CH OH OH xx xo IV
- When cyclohexene is treated with m-chloroperbenzoic acid and H,0, trans-cyclohexane-1,2-diol is produced. Propose a mechanism for this reaction, accounting for the observed stereochemistry. Hint: Recall what a МСРВА + Enantiomer H2O "OH peroxyacid does to an alkene.Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.Identify two alkenes that react with HBr to form 1-bromo-1-methylcyclohexane without undergoing a carbocation rearrangement.
- Consider the following mechanism of reaction: CH3 CH, CH3 CH;C CH, + H-CI CH;CCH, + C: → CH;CCH, tert-butyl cation CI tert-butyl chloride In this reaction: The alkene and the carbocation intermediate are both nucleophilic HCl and CI" are both nucleophilic The alkene and HCI are both electrophilic The carbocation and CI" are both electrophilic The alkene and CI" are both nucleophilic AMeving to another question will save this responseComplete the following reactions, clearly indicating regio-and stereochemistry where applicable. In cases, where ortho-and para-products are formed, draw both.Complete the following reactions, clearly indicating regio-and stereochemistry where applicable. In cases, where ortho-and para-products are formed, draw both.
- Draw the product formed by the reaction of t‑butoxide with (1R,2S)‑1‑bromo‑2‑methyl‑1‑phenylbutane. Draw the correct stereoisomer of the product.To make Halocyclopentane, what reagents and substartes are needed? Which one(below) is related with the Halocyclopentane? Esterification, Alcohol Halogenation ,Alkyl Halide Solvolysis, Alkene Hydration, Hydroboration, Alkene Bromination, Alkene Dihydroxylation, Epoxidation, Diels Alder, Aldol, Grignard Addition, Benzene Nitration, Friedel-Crafts, Carbonyl Reduction, Claisen Condensation, Alcohol OxidationQ12. (1-bromoethyl)benzene 1 udergoes an elimination following an E1 mechanism. Fill in the following synthetic scheme by drawing the structure of intermediate 2 and product 3. The chemical formula of product 3 is provided as guidance. CH; RDS Br C3Hg E1 2 3
