Abs at wavelength 1 ( = Abs at wavelength 2 ( = Sample nm) nm) Cr* Ni2* Unknown Set up the equation for the two wavelengths using Beer's Law and calculate the concentrations of the metal ions in your unknown using two simultaneous equations: at wavelength 1: A1 = A1lccr + Ailcni at wavelength 2: A2 = A2lccr + AzlCNi

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Chapter1: Chemical Foundations
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Abs at wavelength 1
(A =
Abs at wavelength 2
(^ =,
Sample
nm)
nm)
Cr*
Ni2+
Unknown
Set up the equation for the two wavelengths using Beer's Law and calculate the
concentrations of the metal ions in your unknown using two simultaneous equations:
at wavelength 1: A1 = Ailccr + AılCNi
at wavelength 2: A2 = A2lCcr + A2lCNi
Transcribed Image Text:Abs at wavelength 1 (A = Abs at wavelength 2 (^ =, Sample nm) nm) Cr* Ni2+ Unknown Set up the equation for the two wavelengths using Beer's Law and calculate the concentrations of the metal ions in your unknown using two simultaneous equations: at wavelength 1: A1 = Ailccr + AılCNi at wavelength 2: A2 = A2lCcr + A2lCNi
Unknown
Absorbance
STD CURVE Ni
500
650
Mixture:
Compound Cr 0.5 M
Compound Ni 0.5 M
CONC (M)
ABS
ABS
ABS @ 500
0.887
400 nm
0.078
0.213
0.1
0.074
0.091
ABS @ 650
1.078
450 nm
0.111
0.388
0.2
0.148
0.099
500 nm
0.154
0.432
0.4
0.408
0.108
550 nm
0.186
0.367
0.8
1.378
0.127
600 nm
0.264
0.216
1.6
2.413
0.145
650 nm
0.468
0.117
700 nm
0.284
0.087
STD CURVE Cr
500
650
750 nm
0.157
0.057
CONC (M)
ABS
ABS
800 nm
0.154
0.045
0.1
0.075
0.173
0.2
0.103
0.214
0.4
0.106
0.459
0.8
0.124
1.469
1.6
0.189
2.684
Transcribed Image Text:Unknown Absorbance STD CURVE Ni 500 650 Mixture: Compound Cr 0.5 M Compound Ni 0.5 M CONC (M) ABS ABS ABS @ 500 0.887 400 nm 0.078 0.213 0.1 0.074 0.091 ABS @ 650 1.078 450 nm 0.111 0.388 0.2 0.148 0.099 500 nm 0.154 0.432 0.4 0.408 0.108 550 nm 0.186 0.367 0.8 1.378 0.127 600 nm 0.264 0.216 1.6 2.413 0.145 650 nm 0.468 0.117 700 nm 0.284 0.087 STD CURVE Cr 500 650 750 nm 0.157 0.057 CONC (M) ABS ABS 800 nm 0.154 0.045 0.1 0.075 0.173 0.2 0.103 0.214 0.4 0.106 0.459 0.8 0.124 1.469 1.6 0.189 2.684
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