about 232°C. The combustion reaction is: S (s) (s) (g) 2. What happens to the concentration of sulfur and oxygen in a certain period of time? 3. What happens to the amount of sulfur dioxide over a given time? 4. What is the correct expression for the appearance of sulfur dioxide gas? Encircle theletter only. change in concentration of sulfur and oxygen A. Rate of appearance of sulphur dioxide = %3D change in time B. Rate of appearance of sulphur dioxide c hange in concentration of sulfur dioxide change in time

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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ACTIVITY 1 APPEAR OR DISAPPEAR

 

change in time
change in concentration of products
%3D
change in time
The negative sign indicates a decrease in concentration with time. However, rate is always
expressed as a positive quantity. The concentration of all substances is expressedin molar units.
Therefore, units of reaction rates are generally given as mol/(L sec).
Activity 1: Appear or Disappear
Directions: Consider the graph on concentration versus time. Answer the questions
briefly.
RATE OF REACTION
PRODUCTS
REAGENTS
Sulfur is a non-metallic element which burns but does not ignite until heated to
about 232°C. The combustion reaction is:
+ (8) 20 +
SO2 (8)
(s) S
2. What happens to the concentration of sulfur and oxygen in a certain period of time?
3. What happens to the amount of sulfur dioxide over a given time?
4. What is the correct expression for the appearance of sulfur dioxide gas?
Encircle theletter only.
A. Rate of appearance of sulphur dioxide = change in concentration of sulfur and oxygen
change in time
c hange in concentration of sulfur dioxide
B. Rate of appearance of sulphur dioxide=
change in time
Sometimes a particular reactant will have a greater effect on the reaction rate. To show the relationship between reactant
concentrations and the rate of reaction, the rate law is used. This mathematical equation takes the general expression of:
Rate = k [A]m [B] n
where k is the rate constant that is determined experimentally and changes with temperature
A and B are the reactants; and
the powers of m and n are the reaction order.
For example, the following reaction: 2 NO(g) +2 H2(g) > N2(g)+2 H20(g)
By experimental results, it follows the rate law of: Rate k [NO]2 [H2]. Stoichiometric coefficients have nothing to do
with rate law.
Note that doubling the concentration of hydrogen, H2 will only double the rate since its concentration is only taken to the
1st power. However, doubling the concentration of nitric oxide, NO, will cause a fourfold increase in the rate since its
concentration in the rate law is squared.
CONCENTRATION ****
Transcribed Image Text:change in time change in concentration of products %3D change in time The negative sign indicates a decrease in concentration with time. However, rate is always expressed as a positive quantity. The concentration of all substances is expressedin molar units. Therefore, units of reaction rates are generally given as mol/(L sec). Activity 1: Appear or Disappear Directions: Consider the graph on concentration versus time. Answer the questions briefly. RATE OF REACTION PRODUCTS REAGENTS Sulfur is a non-metallic element which burns but does not ignite until heated to about 232°C. The combustion reaction is: + (8) 20 + SO2 (8) (s) S 2. What happens to the concentration of sulfur and oxygen in a certain period of time? 3. What happens to the amount of sulfur dioxide over a given time? 4. What is the correct expression for the appearance of sulfur dioxide gas? Encircle theletter only. A. Rate of appearance of sulphur dioxide = change in concentration of sulfur and oxygen change in time c hange in concentration of sulfur dioxide B. Rate of appearance of sulphur dioxide= change in time Sometimes a particular reactant will have a greater effect on the reaction rate. To show the relationship between reactant concentrations and the rate of reaction, the rate law is used. This mathematical equation takes the general expression of: Rate = k [A]m [B] n where k is the rate constant that is determined experimentally and changes with temperature A and B are the reactants; and the powers of m and n are the reaction order. For example, the following reaction: 2 NO(g) +2 H2(g) > N2(g)+2 H20(g) By experimental results, it follows the rate law of: Rate k [NO]2 [H2]. Stoichiometric coefficients have nothing to do with rate law. Note that doubling the concentration of hydrogen, H2 will only double the rate since its concentration is only taken to the 1st power. However, doubling the concentration of nitric oxide, NO, will cause a fourfold increase in the rate since its concentration in the rate law is squared. CONCENTRATION ****
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