A.) Which parameter between "solvent polarity function" and dielectric constant show better correlation with the peak positions?

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A.) Which parameter between "solvent polarity function" and dielectric constant show better correlation with the peak positions?

B.) When a chromophore binds to proteins, the binding site is generally more hydrophobic than the solution. Then, what kind of shift do you expect to observe in the absorption peak position compared to the peak observed when the chromophore is free in solution?

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