A transition metal chloride (MCI;) combines with pyridine and DMSO to give a metal complex with a formula MCI2(DMSO)»(py). The FT-IR spectrum (in the range from 1425 to 300 cm) of the complex is shown below. L= DMSO MCI, + py + 3L py=N
A transition metal chloride (MCI;) combines with pyridine and DMSO to give a metal complex with a formula MCI2(DMSO)»(py). The FT-IR spectrum (in the range from 1425 to 300 cm) of the complex is shown below. L= DMSO MCI, + py + 3L py=N
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![3. A transition metal chloride (MCI2) combines with pyridine and DMSO to give a metal
complex with a formula MCI2(DMSO)(py). The FT-IR spectrum (in the range from 1425
to 300 cm-') of the complex is shown below.
to
CI
L = DMSO
MCI, + py + 3L
py = N
1400
1200
1000
800
600
400
wavenumber / cm
(a) Based on the spectral information above, through which atom do the DMSO ligand
bond to central M' ion?
(b) Explain your answer in (a) above..](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe6c5ff51-13cf-4175-ab2a-d4efcda13885%2F2af8e570-fc55-4d05-995c-0644cbcdecc1%2Ffrlix7t_processed.jpeg&w=3840&q=75)
Transcribed Image Text:3. A transition metal chloride (MCI2) combines with pyridine and DMSO to give a metal
complex with a formula MCI2(DMSO)(py). The FT-IR spectrum (in the range from 1425
to 300 cm-') of the complex is shown below.
to
CI
L = DMSO
MCI, + py + 3L
py = N
1400
1200
1000
800
600
400
wavenumber / cm
(a) Based on the spectral information above, through which atom do the DMSO ligand
bond to central M' ion?
(b) Explain your answer in (a) above..
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