4 3. A transition metal chloride (MCI2) combines with pyridine and DMSO to give a metalcomplex with a formula MCI2(DMSO)(py). The FT-IR spectrum (in the range from 1425to 300 cm-') of the complex is shown below.toCIL = DMSOMCI, + py + 3Lpy = N140012001000800600400wavenumber / cm(a) Based on the spectral information above, through which atom do the DMSO ligandbond to central M' ion?(b) Explain your answer in (a) above..

To which atom does the DMSO ligand bond to central M2+ ion.

A transition metal chloride (MCI;) combines with pyridine and DMSO to give a metal complex with a formula MCI2(DMSO)»(py). The FT-IR spectrum (in the range from 1425 to 300 cm) of the complex is shown below. L= DMSO MCI, + py + 3L py=N

A transition metal chloride (MCI;) combines with pyridine and DMSO to give a metal complex with a formula MCI2(DMSO)»(py). The FT-IR spectrum (in the range from 1425 to 300 cm) of the complex is shown below. L= DMSO MCI, + py + 3L py=N

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

3. A transition metal chloride (MCI2) combines with pyridine and DMSO to give a metal
complex with a formula MCI2(DMSO)(py). The FT-IR spectrum (in the range from 1425
to 300 cm-') of the complex is shown below.
to
CI
L = DMSO
MCI, + py + 3L
py = N
1400
1200
1000
800
600
400
wavenumber / cm
(a) Based on the spectral information above, through which atom do the DMSO ligand
bond to central M' ion?
(b) Explain your answer in (a) above..

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