a) The kinetic behaviour for the depolymerization of lignocellulosic biomass in a batch reactor and continuous tank reactor (CSTR) will be initially determined and analysed under optimized process conditions. As a process engineer, propose a complete batch reactor and CSTR design analysis (including the reaction time) and estimate the production capacity (kg per day) of the levulinic acid (LA). For the safety practise in chemical plant, the working volume is intended for 85% of the reactor volume and the conversion must achieve at least 95%. The reaction is isothermal at 450 K, and the initial composition of water to HMF is fixed at a ratio of 1:4. The reaction is a second-order with respect to the concentration of HMF. Provide a complete reactor design analysis for both batch reactor and CSTR starting from the derivation of the design equations. Choose the preferable reactor and justify your answer. Plot the concentration profile (concentration versus conversion) of the reactants and products as the reaction taking place in the reactor. Use Microsoft Excel or any suitable software toplot the graph. HMF + 2H₂0 LA LA+FA Given, k=0.12 L. mol-³¹. min-¹ at temperature of 350 K. E. 37 kJ/mol.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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a) The kinetic behaviour for the depolymerization of lignocellulosic biomass in
a batch reactor and continuous tank reactor (CSTR) will be initially
determined and analysed under optimized process conditions. As a process
engineer, propose a complete batch reactor and CSTR design analysis
(including the reaction time) and estimate the production capacity (kg per
day) of the levulinic acid (LA). For the safety practise in chemical plant, the
working volume is intended for 85% of the reactor volume and the conversion
must achieve at least 95%. The reaction is isothermal at 450 K, and the initial
composition of water to HMF is fixed at a ratio of 1:4. The reaction is a
second-order with respect to the concentration of HMF. Provide a complete
reactor design analysis for both batch reactor and CSTR starting from the
derivation of the design equations. Choose the preferable reactor and justify
your answer. Plot the concentration profile (concentration versus conversion)
of the reactants and products as the reaction taking place in the reactor. Use
Microsoft Excel or any suitable software to plot the graph.
HMF + 2H;0 LA + FA
Given,
k=0.12 L. mol. min- at temperature of 350 K.
E:= 37 kJ/mol.
Transcribed Image Text:a) The kinetic behaviour for the depolymerization of lignocellulosic biomass in a batch reactor and continuous tank reactor (CSTR) will be initially determined and analysed under optimized process conditions. As a process engineer, propose a complete batch reactor and CSTR design analysis (including the reaction time) and estimate the production capacity (kg per day) of the levulinic acid (LA). For the safety practise in chemical plant, the working volume is intended for 85% of the reactor volume and the conversion must achieve at least 95%. The reaction is isothermal at 450 K, and the initial composition of water to HMF is fixed at a ratio of 1:4. The reaction is a second-order with respect to the concentration of HMF. Provide a complete reactor design analysis for both batch reactor and CSTR starting from the derivation of the design equations. Choose the preferable reactor and justify your answer. Plot the concentration profile (concentration versus conversion) of the reactants and products as the reaction taking place in the reactor. Use Microsoft Excel or any suitable software to plot the graph. HMF + 2H;0 LA + FA Given, k=0.12 L. mol. min- at temperature of 350 K. E:= 37 kJ/mol.
1) BioPro Sdn. Bhd. is interested in expanding their business by manufacturing a
medium-scale production capacity to produce levulinic acid (LA). LA is a versatile
building block that for decades has been considered a basic raw chemical material
owing to its high chemical reactivity. This renewable biochemical can be used as a
platform to produce various high-volume organic chemicals with numerous potential
industrial applications. For instance, LA can serve as a feedstock for a production
of transportation fuels such as gasoline and diesel.
Glucose
HMF
Levulinic Acid
Formic Acid
но
HO
k2
он
HO
HO
OH
OH
Decomposition
Products (humins)
Glucose HMF + 3H20
(Equation 1)
HMF + 2H,0 LA + FA
(Equation 2)
HMF Decomposition products (humins)
(Equation 3)
The formation of levulinic acid (LA) from carbohydrates consists of a series of
consecutive reactions, which includes glucose dehydration step to produce 5-
hydroxymethylfurfural (HMF) as shown in Equation 1. Equation 2 represents the
rehydration of HMF with two molecules of water (H2O) to produce LA and formic
acid (FA). The formation of undesired highly polymerized carbonaceous species
(for example, humins) from HMF dehydration as indicated in Equation 3 has been
reported in the literature. This work investigates the in-situ reaction mechanism of
depolymerization of agricultural waste using a one-pot approach that includes both
quick and slow hydrolysis. Kinetic and reaction mechanism were studied to scale
up the production of HMF.
Transcribed Image Text:1) BioPro Sdn. Bhd. is interested in expanding their business by manufacturing a medium-scale production capacity to produce levulinic acid (LA). LA is a versatile building block that for decades has been considered a basic raw chemical material owing to its high chemical reactivity. This renewable biochemical can be used as a platform to produce various high-volume organic chemicals with numerous potential industrial applications. For instance, LA can serve as a feedstock for a production of transportation fuels such as gasoline and diesel. Glucose HMF Levulinic Acid Formic Acid но HO k2 он HO HO OH OH Decomposition Products (humins) Glucose HMF + 3H20 (Equation 1) HMF + 2H,0 LA + FA (Equation 2) HMF Decomposition products (humins) (Equation 3) The formation of levulinic acid (LA) from carbohydrates consists of a series of consecutive reactions, which includes glucose dehydration step to produce 5- hydroxymethylfurfural (HMF) as shown in Equation 1. Equation 2 represents the rehydration of HMF with two molecules of water (H2O) to produce LA and formic acid (FA). The formation of undesired highly polymerized carbonaceous species (for example, humins) from HMF dehydration as indicated in Equation 3 has been reported in the literature. This work investigates the in-situ reaction mechanism of depolymerization of agricultural waste using a one-pot approach that includes both quick and slow hydrolysis. Kinetic and reaction mechanism were studied to scale up the production of HMF.
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