(a) Show that z = N/Q. where Is called the partition function. (b) Show that the internal energy per particle is given by U N InQ de (c) For a polyatomic molecule, the energy has contributions from translational motion, and internal degrees of freedom such as rotations and vibrations: € = Etrans + Erot + Cvib Show that the partition function factorizes, and the specific heat capacity decomposes into a sum of terms: Q = Qtrans Qrot Qvib. Cy = Ctrans + Crot + Cutb

(a) Show that z = N/Q. where Is called the partition function. (b) Show that the internal energy per particle is given by U N InQ de (c) For a polyatomic molecule, the energy has contributions from translational motion, and internal degrees of freedom such as rotations and vibrations: € = Etrans + Erot + Cvib Show that the partition function factorizes, and the specific heat capacity decomposes into a sum of terms: Q = Qtrans Qrot Qvib. Cy = Ctrans + Crot + Cutb

College Physics

11th Edition

ISBN:9781305952300

Author:Raymond A. Serway, Chris Vuille

Publisher:Raymond A. Serway, Chris Vuille

Chapter1: Units, Trigonometry. And Vectors

Section: Chapter Questions

Problem 1CQ: Estimate the order of magnitude of the length, in meters, of each of the following; (a) a mouse, (b)...

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