A sensitive method for 12 in the presence of Cl₂ and Br₂ entails oxidation of the 12 to 103 with Br₂. The excess Br₂ is then removed by boiling or by reduction with formate ion. The 103 produced is determined by addition of excess 1₂ and titration of the resulting 1₂. A 1.307-g sample of mixed halides was dissolved and analyzed by the foregoing procedure. A volume of 19.72 mL of 0.04926 M thiosulfate was required for the titration. Calculate the percentage of KI in the sample.

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A sensitive method for 12 in the presence of Cl₂ and Br₂ entails oxidation of the 1₂ to 103 with Br₂.
The excess Br₂ is then removed by boiling or by reduction with formate ion. The 103 produced is
determined by addition of excess 1₂ and titration of the resulting 1₂. A 1.307-g sample of mixed
halides was dissolved and analyzed by the foregoing procedure. A volume of 19.72 mL of 0.04926
M thiosulfate was required for the titration. Calculate the percentage of KI in the sample.
Transcribed Image Text:A sensitive method for 12 in the presence of Cl₂ and Br₂ entails oxidation of the 1₂ to 103 with Br₂. The excess Br₂ is then removed by boiling or by reduction with formate ion. The 103 produced is determined by addition of excess 1₂ and titration of the resulting 1₂. A 1.307-g sample of mixed halides was dissolved and analyzed by the foregoing procedure. A volume of 19.72 mL of 0.04926 M thiosulfate was required for the titration. Calculate the percentage of KI in the sample.
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