A sensitive method for 12 in the presence of Cl₂ and Br₂ entails oxidation of the 12 to 103 with Br₂. The excess Br₂ is then removed by boiling or by reduction with formate ion. The 103 produced is determined by addition of excess 1₂ and titration of the resulting 1₂. A 1.307-g sample of mixed halides was dissolved and analyzed by the foregoing procedure. A volume of 19.72 mL of 0.04926 M thiosulfate was required for the titration. Calculate the percentage of KI in the sample.
A sensitive method for 12 in the presence of Cl₂ and Br₂ entails oxidation of the 12 to 103 with Br₂. The excess Br₂ is then removed by boiling or by reduction with formate ion. The 103 produced is determined by addition of excess 1₂ and titration of the resulting 1₂. A 1.307-g sample of mixed halides was dissolved and analyzed by the foregoing procedure. A volume of 19.72 mL of 0.04926 M thiosulfate was required for the titration. Calculate the percentage of KI in the sample.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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