A solution containing a mixture of metal cations was treated as outlined. 1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off. 2. H,S was bubbled through the acidic solution. No precipitate formed. 3. The pH was raised to about 9 and H,S was again bubbled through the solution. A precipitate formed and was filtered off. 4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off. What can be said about the presence of each of these groups of cations in the original solution? Cation group Description Present in the original solution? Ag+, Pb?+, Hg3+ ,2+ form insoluble chlorides Bi3+, Cd²+, Cu²+, Hg²+, Pb2+, Sb3+, Sn²+, Sn++ Al3+, Co2+, Cr3+, Fe2+, Fe3+, Ni2+, Mn2+, Zn²+ form acid-insoluble sulfides form base-insoluble sulfides or hydroxides Ba2+, Ca2+, Mg²+, Sr²+ form insoluble carbonates Lit, Na*, K*, NH completely soluble Answer Bank unknown At least one of these ions was present. All of these ions were present. None of these ions were present.

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A solution containing a mixture of metal cations was treated as outlined.
1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off.
2. H,S was bubbled through the acidic solution. No precipitate formed.
3. The pH was raised to about 9 and H,S was again bubbled through the solution. A precipitate formed and was filtered off.
4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off.
What can be said about the presence of each of these groups of cations in the original solution?
Cation group
Description
Present in the original solution?
Ag+, Pb?+, Hg3+
,2+
form insoluble chlorides
Bi3+, Cd²+, Cu²+, Hg²+,
Pb2+, Sb3+, Sn²+, Sn++
Al3+, Co2+, Cr3+, Fe2+,
Fe3+, Ni2+, Mn2+, Zn²+
form acid-insoluble sulfides
form base-insoluble sulfides
or hydroxides
Ba2+, Ca2+, Mg²+, Sr²+
form insoluble carbonates
Lit, Na*, K*, NH
completely soluble
Answer Bank
unknown
At least one of these ions
was present.
All of these ions were
present.
None of these ions were
present.
Transcribed Image Text:A solution containing a mixture of metal cations was treated as outlined. 1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off. 2. H,S was bubbled through the acidic solution. No precipitate formed. 3. The pH was raised to about 9 and H,S was again bubbled through the solution. A precipitate formed and was filtered off. 4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off. What can be said about the presence of each of these groups of cations in the original solution? Cation group Description Present in the original solution? Ag+, Pb?+, Hg3+ ,2+ form insoluble chlorides Bi3+, Cd²+, Cu²+, Hg²+, Pb2+, Sb3+, Sn²+, Sn++ Al3+, Co2+, Cr3+, Fe2+, Fe3+, Ni2+, Mn2+, Zn²+ form acid-insoluble sulfides form base-insoluble sulfides or hydroxides Ba2+, Ca2+, Mg²+, Sr²+ form insoluble carbonates Lit, Na*, K*, NH completely soluble Answer Bank unknown At least one of these ions was present. All of these ions were present. None of these ions were present.
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