A solution containing a mixture of metal cations was treated as outlined. 1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off. 2. H,S was bubbled through the acidic solution. No precipitate formed. 3. The pH was raised to about 9 and H,S was again bubbled through the solution. A precipitate formed and was filtered off. 4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off. What can be said about the presence of each of these groups of cations in the original solution? Cation group Description Present in the original solution? Ag+, Pb?+, Hg3+ ,2+ form insoluble chlorides Bi3+, Cd²+, Cu²+, Hg²+, Pb2+, Sb3+, Sn²+, Sn++ Al3+, Co2+, Cr3+, Fe2+, Fe3+, Ni2+, Mn2+, Zn²+ form acid-insoluble sulfides form base-insoluble sulfides or hydroxides Ba2+, Ca2+, Mg²+, Sr²+ form insoluble carbonates Lit, Na*, K*, NH completely soluble Answer Bank unknown At least one of these ions was present. All of these ions were present. None of these ions were present.
A solution containing a mixture of metal cations was treated as outlined. 1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off. 2. H,S was bubbled through the acidic solution. No precipitate formed. 3. The pH was raised to about 9 and H,S was again bubbled through the solution. A precipitate formed and was filtered off. 4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off. What can be said about the presence of each of these groups of cations in the original solution? Cation group Description Present in the original solution? Ag+, Pb?+, Hg3+ ,2+ form insoluble chlorides Bi3+, Cd²+, Cu²+, Hg²+, Pb2+, Sb3+, Sn²+, Sn++ Al3+, Co2+, Cr3+, Fe2+, Fe3+, Ni2+, Mn2+, Zn²+ form acid-insoluble sulfides form base-insoluble sulfides or hydroxides Ba2+, Ca2+, Mg²+, Sr²+ form insoluble carbonates Lit, Na*, K*, NH completely soluble Answer Bank unknown At least one of these ions was present. All of these ions were present. None of these ions were present.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:A solution containing a mixture of metal cations was treated as outlined.
1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off.
2. H,S was bubbled through the acidic solution. No precipitate formed.
3. The pH was raised to about 9 and H,S was again bubbled through the solution. A precipitate formed and was filtered off.
4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off.
What can be said about the presence of each of these groups of cations in the original solution?
Cation group
Description
Present in the original solution?
Ag+, Pb?+, Hg3+
,2+
form insoluble chlorides
Bi3+, Cd²+, Cu²+, Hg²+,
Pb2+, Sb3+, Sn²+, Sn++
Al3+, Co2+, Cr3+, Fe2+,
Fe3+, Ni2+, Mn2+, Zn²+
form acid-insoluble sulfides
form base-insoluble sulfides
or hydroxides
Ba2+, Ca2+, Mg²+, Sr²+
form insoluble carbonates
Lit, Na*, K*, NH
completely soluble
Answer Bank
unknown
At least one of these ions
was present.
All of these ions were
present.
None of these ions were
present.
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY