A reaction, 2NO (g) + O2 (g) 2NO2 (g), was run in a laboratory setting. Given the following plausible mechanism, answer the following questions: Step 1: NO (g) + NO (g) N202 (g) (fast) Step 2: N202 (g) + O2 (g) 2NO2 (g) (slow) (i) Determine the rate law for the above reaction. (ii) Identify the reaction intermediates. (iii) If the speeds of the elementary steps were switched (i.e. elementary step 1 was slow and step 2 was fast), could this reaction mechanism still be plausible? Explain your answer.
A reaction, 2NO (g) + O2 (g) 2NO2 (g), was run in a laboratory setting. Given the following plausible mechanism, answer the following questions: Step 1: NO (g) + NO (g) N202 (g) (fast) Step 2: N202 (g) + O2 (g) 2NO2 (g) (slow) (i) Determine the rate law for the above reaction. (ii) Identify the reaction intermediates. (iii) If the speeds of the elementary steps were switched (i.e. elementary step 1 was slow and step 2 was fast), could this reaction mechanism still be plausible? Explain your answer.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:A reaction, 2NO (g) + O2 (g) → 2NO: (g), was run in a laboratory setting. Given the
following plausible mechanism, answer the following questions:
Step 1: NO (g) + NO (g)
N202 (g) (fast)
k.
Step 2: N202 (g) + O2 (g)
2NO2 (g) (slow)
(i)
Determine the rate law for the above reaction.
(ii)
Identify the reaction intermediates.
(iii)
If the speeds of the elementary steps were switched (i.e. elementary step 1 was slow
and step 2 was fast), could this reaction mechanism still be plausible? Explain your
answer.
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