A quality control (QC) sample was run in replicates of six to produce the following concentrations values: 12.2, 11.6, 11.9, 12.3, 12.8, and 11.7 ug/L. Is this level of analytical method precision acceptable for this group of QC replicates? O 3.3%, YES O 3.3%, NO O 5.5%, YES O 5.5% NO
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- To test the quality of the work of a commercial laboratory, duplicate analyses of apurified benzoic acid (68.8% C, 4.953% H) sample were requested. It is assumed that therelative standard deviation of the method is sr → = 4 ppt for carbon and 6 ppt forhydrogen. The means of the reported results are 68.5% C and 4.882% H. At the 95%confidence level, is there any indication of systematic error in either analysis?Analysis of several plant-food preparations for potassium ion yielded the following data: Sample Percent K+1 6.02, 6.04, 5.88, 6.06, 5.822 5.29, 5.13, 5.14, 5.28, 5.20 The preparations were randomly drawn from the same population.(a) Find the mean and standard deviation s , variance , andCV for each sample.[References) A method for the determination of the corticosteroid methylprednisolone acetate in solutions obtained from pharmaceutical preparations yielded a mean value of 3.7 mg mL with a standard deviation of 0.3 mg mL. For quality control purposes, the relative uncertainty in the concentration should be no more than 3%. How many samples of each batch should be analyzed to ensure that the relative standard deviation does not exceed 9% at the 95% confidence level? samples
- For the determination of iron in used jet engine oil, 30 analyzes with 3 repetitions each were made by atomic absorption method and the standard deviation was found s=2.4 µg Fe/mL. Since this standard deviation value is close to the ϭ value, the iron concentration of 18.5 µg Fe/mL(a) by a single analysis,(b) as the average of the two analyzes,(c) Calculate the 80% and 95% confidence intervals if found as the mean of four analyses.A titrimetric method for the determination of calcium in limestone was tested with the analysis of a NIST limestone containing 30.15% CaO. The mean of the four analyzes is 30.26% CaO with a standard deviation of 0.085%. From the data accumulated from many analyzes, s→ϭ=0.094% CaO was found.a) Do the data indicate the presence of systematic error at the 95% confidence level?b) When a value for ϭ is unknown, do the data show a systematic error at the 95% confidence level?Determine the correct answer for the following.question: A quality control (QC) sample was run in replicates of six to produce the following concentrations values: 12.2, 11.6, 11.9, 12.3, 12.8, and 11.7 ug/L. Is this level of analytical method precision acceptable for this group of QC replicates? O 3.3%, YES O 3.3%, NO O 5.5%, YES O 5.5% NO Question 9 Determine the correct answer for the following question: One definition of analytical method accuracy in a GLP laboratory is +20 percent relative error (RE) of the measured mean sample concentration to that of the true concentration such that %re = [(Measured Mean Concentration - True Concentration)/True Concentration] x 100 A single quality control (QC) sample was prepared at a concentration of 12.5 ug/Land run in replicates of six to produce the following concentrations values: 12.5, 11.9, 14.2, 12.2, 13.7, and 14.1 ug/L. Is this level of analytical method accuracy acceptable for this QC sample?
- A young researcher was evaluating a standard method for determining the methylmercury content in blue fin tuna using high performance liquid chromatography (HPLC). She determined the standard deviation (?)(s) for the method to be 0.440.44 ppb and assumed that ?s was a good approximation of ?σ . As a test, she used this method to evaluate the methylmercury content in a National Institutes of Standards and Technology (NIST) standard and determined the unknown amount to be within 0.210.21 ppb (?)(μ) of the known mean with 99% probability. How many replicate measurements of the NIST standard did the researcher perform?A volume of 250 ml of a 0.05 M solution of a reagent of formula weight (relative molecular mass) 40 was made up, the weighing being done by difference. The standard deviation of each weighing was 0.0001 g. 1 (a) What were the standard deviation and relative standard deviation of the weight of reagent used?10) The following results were obtained in an analysis of iron content in an ore sample. The results reported as % Fe for each analysis, were as follow: Samples no. 1 3 4 5 6 % Fe 20.10 20.50 18.65 19.25 19.40 19.99 i. Calculate the mean and median from the set of the data above ii. If the true value of %Fe is 19.65 %, calculate the value for absolute error and percentage relative error for sample no. 3 Using Q-test, justify whether an of the data must be rejected at 95 % ii. confidence level iv. Calculate the standard deviation and relative standard deviation of the data.
- Analysis of several plant-food preparations for potassium ion yielded the following data: Sample Percent K+ 1 3.90, 3.96, 4.16, 3.96 2 4.48, 4.65, 4.68, 4.42 Find the mean ; standard deviation variance and RSD for each sample.Pesticide residues were found in a lot of oranges; the compound identified was the epoxide of heptachlor (EH). To quantify the amount of this pesticide in oranges, 20 grams were taken from fruit peels and mixed with methylene chloride to extract it. The concentration of heptachlor epoxide in the sample was determined by gas chromatography coupled to a detector mass (GC-MS); and calibration was performed using anthracene (A) as internal standard. For In this analysis, the anthracene had a concentration of 350 ppm and the same volume was added to each standard. The table below shows the concentrations of the standard and the ratio of the areas.and the sample is: 0.1080.Determine the concentration of heptachlor epoxide in the sample.Suppose a difference in changes in plasma oxytocin levels between two groups of 0.2 pg/mL would be of interest to researchers and that changes within each group have standard deviation o = 0.1 pg/mL. The power of a one-sided two-sample t-test to detect a difference in changes in oxytocin levels of 0.2 pg/mL between two groups of 5 women at the 5% level is