In the HQS-Mg fluorescence part of Lab 6, a calibration curve is made of fluorescence intensity vs.MgCl2 concentration (M). The standard solutions for the calibration curve were made by mixing asmall amount of 0.01 M MgCl2 with some HQS solution. Calculate the concentration of MgCl2 (M)in each of the following standards. Report your concentrations to 3 sig figs.FluorescenceVolume of 0.01 MVolume of 1 mMConcentration of MgCl2 (M)IntensityMgCl2 (mL)HQS (mL)0.0312509020.81000.0494907540.8500.05980350721000.0858340293.6100Hint: The total volume of each solution is volume of 0.01 M MgCl2 + volume of 1 mM HQS.

The objective of this question is to show the experiment, a series of standard solutions are…

In the HQS-Mg fluorescence part of Lab 6, a calibration curve is made of fluorescence intensity vs. MgCl₂ concentration (M). The standard solutions for the calibration curve were made by mixing a small amount of 0.01 M MgCl₂ with some HQS solution. Calculate the concentration of MgCl₂ (M) in each of the following standards. Report your concentrations to 3 sig figs.

In the HQS-Mg fluorescence part of Lab 6, a calibration curve is made of fluorescence intensity vs. MgCl₂ concentration (M). The standard solutions for the calibration curve were made by mixing a small amount of 0.01 M MgCl₂ with some HQS solution. Calculate the concentration of MgCl₂ (M) in each of the following standards. Report your concentrations to 3 sig figs.

Appl Of Ms Excel In Analytical Chemistry

2nd Edition

ISBN:9781285686691

Author:Crouch

Publisher:Crouch

Chapter12: Spectrochemical Methods

Section: Chapter Questions

Problem 11P

See similar textbooks

Similar questions

The chromium in an aqueous sample was determined by pipetting 10.0 ml. of the unknown into each of five 50.0-mL volumetric flasks. Various volumes of a standard containing 12.2 ppm Cr were added to the flasks, following which the solutions were diluted to volume. Unknown,mLStandard, mLAbsorbancc 10.00.00.201 10.010.0 0.292 10.020.0 0.378 10.030.0 0.467 10.040.0 0.554 (a) Plot the data using a spreadsheet. (b) Determine an equation for the relationship between absorbance and volume of standard. (c) Calculate the statistics for the least-squares relationship in (b). (d) I)ctcrmine the conccnt ration oÍCr in ppm in the sample. (e) Find the standard deviation of the result in (d).
Quinine in a 1.553-g antimalarial tablet was dissolved in sufficient 0.10 M HCl to give 250 mL of solution.A 10.00-mL aliquot was then diluted to 50.00 mL with the acid. The fluorescence intensity for the dilutedsample at 347.5 nm provided a reading of 196 on an arbitrary scale. A standard 100-ppm quinine solutionregistered 125 when measured under conditions identical to those for the diluted sample. Calculate the massin milligrams of quinine in the tablet.
Exactly 5.00 mL aliquots of a solution containing analyte X were transferred into 50.00-mL volumetric flasks and the pH of the solution is adjusted to 9.0. The following volumes of a standard solution containing 2.00 µg/mL of X were then added into each flask and the mixture was diluted to volume: 0.000, 0.500, 1.00, 1.50 and 2.00 mL. The fluorescence of each of these solutions was measured with a fluorometer, and the following values were obtained: 3.26, 4.80, 6.42, 8.02 and 9.56, respectively. ii. Using relevant functions in Excel, derive a least-squares equation for the data, and use the parameters of this equation to find the concentration of the phenobarbital in the unknown solution.
The Na* concentration in a blood serum sample was determined using the method of standard addition and atomic spectroscopy. 25.00 mL aliquots of serum were pipetted into five 50.00 mL volumetric flasks into which 2.640 M NaCl standard was added as shown in the table below. After dilution to volume, the emission of each solution was measured and used to plot a calibration graph. Flask 1 23 4 5 Vol. of standard (mL) 0 1.00 2.00 3.00 4.00 Emission signal 3.13 5.40 7.89 10.30 12.48 Analytical signal (emission) 14 42 10 12 4 2 0 0 0.05 y = 44.697x + 3.12 R² = 0.9995 0.1 0.15 Concentration of added analyte (M) 0.2 a) Using the plotted calibration graph, calculate the Na* concentration in the blood serum sample. b) Provide a possible reason why the serum sample might have been analysed using this analytical procedure. 0.25
1FbhGb6cd_1-5c/IV_Ivqu J4002epq/z4kbhpYZSIA opy ✩✩ IS Extensions Help I text Calibri. 12 +BIU A d f5 A % 5 T f6 1 5 J 1. Why is it recommended to have a carbon monoxide detector on each floor of a home? Page 4: Water Pollution: Questions i M 6 2. What impact would the increased use of electric vehicles have on environmental damage caused by acid rain? Page 3: More Air Pollution Issues: Questions 4. The COVID-19 pandemic forced many people to work from home for extended periods. During these periods, many cities reported unusually low levels of smog. Suggest an explanation for this observation. 5. Explain how ozone can be both harmful and beneficial. 3. Why is ground level ozone most likely to reach its highest concentrations on hot, sunny days during periods of heavy traffic in large cities? f7 Y []») 3 6. India relies heavily on burning coal to generate electricity. How does India's reliance on coal contribute to the poor air quality experienced in many of India's major cities? & 7 18…
To determine the instrument detection limit of Pb2+ ions, a student made 10 blank solutions and measured their signals. The standard deviation of the signals are 0.199. Then the student made a series of Pb2+ standard solutions (concentration range is 2.00 ppm to 15.00 ppm) and measured their signals. The equation of the calibration curve is: y = 3.413 x+ (b). What is the instrument detection limit of Pb2+ in ppm? %3D
The validation process comprises four main steps that are : hardware validation, software validation, method validation and system suitability. To evaluate a spectrophotometer’s accuracy by measuring absorbance, a solution of 60.06 mg/L K2Cr2O7 in 0.0050M H2SO4 was carefully prepared together with a 0.0050 M H2SO4 as a reagent blank. If the spectrometer’s signal is properly calibrated, it has been reported that this solution should provide an absorbance of 0.640 +- 0.010 at wavelength 350 nm. Which one of the validations mentioned above had been involved in this process? Explain your choice
show-all-working-explaining-detailly-each-step Answer should be typewritten using a computer keyboard.
None
Consider the reaction : A+B 2 AB. A calibration plot was constructed using x as the concentration for AB in M and y as the absorbance value of AB, it provided the linear equation : y=25x+0.0008. Determine the concentration of AB in M if the absorbance value is 1.22. Round and report your value to the THIRD decimal place. Numeric value only, no unit. No new data to sa IMG 0915.jpeg e to search PrtScn Home
In the process of performing a spectrophotometric determination of Fe, an analyst prepares a calibration curve using a single-beam spectrometer, such as a Spec-20. After preparing the calibration curve, the analyst drops the cuvette used for the method blank and the standards. The analyst acquires a new cuvette, measures the absorbance of the sample, and determines the %w/w Fe in the sample. Will the change in cuvette lead to a determinate error in the analysis? Explain.
5 What would the effect of increasing sample pressure (while maintaining a fixed cell length) have on an FTIR spectrum. By ”cell” I mean the chamber holding the gas.