(a) Provide a curved arrow mechanism for the reaction shown below, commenting on the stereochemical outcome. Aco Aco AcO- AcO- OAC PhSH, BF3 OEt2 CH₂Cl₂ ACO ACO ACO ACO Ho ŠPh Major product (b) Which spectroscopic technique would you use to determine the stereochemistry at the anomeric centre of a sugar? Describe what
(a) Provide a curved arrow mechanism for the reaction shown below, commenting on the stereochemical outcome. Aco Aco AcO- AcO- OAC PhSH, BF3 OEt2 CH₂Cl₂ ACO ACO ACO ACO Ho ŠPh Major product (b) Which spectroscopic technique would you use to determine the stereochemistry at the anomeric centre of a sugar? Describe what
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:4.
(a) Provide a curved arrow mechanism for the reaction shown below,
commenting on the stereochemical outcome.
Aco Aco
AcO-
ACO
OAC
PhSH, BF3 OEt2
CH₂Cl2
Aco Aco
AcO-
ACO
SPh
Major product
(b) Which spectroscopic technique would you use to determine the
stereochemistry at the anomeric centre of a sugar? Describe what
you would expect to see for a-D-glucopyranose and why.
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