Draw the major product(s) of the following reactions, if there is a reaction. Be sure to include stereochemistry in your products. CEN H30* 32 NaOH но он H. H30*
Draw the major product(s) of the following reactions, if there is a reaction. Be sure to include stereochemistry in your products. CEN H30* 32 NaOH но он H. H30*
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:**Transcription for Educational Website**
---
**Instructions:**
Draw the **major product(s)** of the following reactions, if there is a reaction. **Be sure to include stereochemistry in your products.**
---
**Reactions:**
1. Cyclopentanecarbonitrile (a five-membered ring with a cyanide group) reacting with \( \text{H}_3\text{O}^+ \).
2. Methyl ketone with a benzene ring on one side reacts with \( 3 \, \text{I}_2 \) / \( \text{NaOH} \).
3. Propanal (a three-carbon aldehyde) with ethylene glycol in the presence of \( \text{H}_3\text{O}^+ \).
4. Cyclohexanone reacts in two steps:
- Step 1: \( \text{LDA} \), \( \text{THF} \)
- Step 2: 2-methylpropanal (a four-carbon aldehyde with a methyl group on the second carbon).
---
**Explanation of Diagrams and Reactions:**
- **Diagram 1:** The structure shows a cyclopentane ring with a nitrile group (\(-C \equiv N\)). When hydrolyzed with \( \text{H}_3\text{O}^+ \), it will likely result in a carboxylic acid.
- **Diagram 2:** The compound is a phenyl methyl ketone. The reaction conditions suggest iodination under basic conditions, likely leading to the formation of iodoform and a carboxylate ion.
- **Diagram 3:** Shows aldehyde protection as an acetal. Propanal reacts with ethylene glycol in acidic conditions leading to the formation of a cyclic acetal.
- **Diagram 4:** This is an enolate formation followed by an aldol reaction. Cyclohexanone forms its enolate with LDA, then reacts with 2-methylpropanal to form a β-hydroxy ketone.
**Note:** For all reactions, consider any possible stereochemical outcomes and depict them in your structural representations.
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 1 images

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY