A mixture of nitric and sulfuric acids generates the nitroniium ion, +NO₂ (mechanism provided), which can react with benzene to form nitrobenzene via electrophilic aromatic substitution. Using the provided mechanism that forms the nitronium ion, give a full curved-arrow pushing mechanism for the reaction shown below, indicate the Lewis and Bronsted acids/bases at each step as appropriate (LA, LB, BA, BB) and include all important resonance contributors at any ionic intermediates. To preview the image click here : OH O-N+ S-OH HNO3 H₂SO4 OH ₂ NO₂ .. O=N=O + HSO4 nitronium ion electrophile

A mixture of nitric and sulfuric acids generates the nitroniium ion, +NO₂ (mechanism provided), which can react with benzene to form nitrobenzene via electrophilic aromatic substitution. Using the provided mechanism that forms the nitronium ion, give a full curved-arrow pushing mechanism for the reaction shown below, indicate the Lewis and Bronsted acids/bases at each step as appropriate (LA, LB, BA, BB) and include all important resonance contributors at any ionic intermediates. To preview the image click here : OH O-N+ S-OH HNO3 H₂SO4 OH ₂ NO₂ .. O=N=O + HSO4 nitronium ion electrophile

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Amines

Amines are organic compounds with a nitrogen atom having a lone pair of electrons on it. They are derived from ammonia (NH3) wherein hydrogen atoms are substituted by an aryl or alkyl group.

Question

A mixture of nitric and sulfuric acids generates the nitroniium ion,
+NO₂ (mechanism provided), which can react with benzene to
form nitrobenzene via electrophilic aromatic substitution. Using
the provided mechanism that forms the nitronium ion, give a full
curved-arrow pushing mechanism for the reaction shown below,
indicate the Lewis and Bronsted acids/bases at each step as
appropriate (LA, LB, BA, BB) and include all important resonance
contributors at any ionic intermediates.
To preview the image click here
: OH
O-N+
S-OH
HNO3
H₂SO4
OH₂
NO₂
O=N=O + HSO4
nitronium ion
electrophile

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