1. During the first part of the mechanism in the reaction above, the catalyst forms a complex using hydrogen bonds. On the lines below the catalyst and the nitro alkene, label them as the Lewis Acid and/or Lewis Base. HN- NO2 Ph + Ar then proton transfer NO2 Ph

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Chapter1: Chemical Foundations
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Reaction Scheme:
ÇF3
ÇF3
HN-
10 mol % urea
NO2
+
Ph
CH2CI2, 23 °C
CF3CH2OH, 24 h
43% yield
F3C°
`CF3
Ph
ZON
urea catalyst
1. During the first part of the mechanism in the reaction above, the catalyst forms a complex using
hydrogen bonds. On the lines below the catalyst and the nitro alkene, label them as the Lewis Acid
and/or Lewis Base.
Ar
Ar
HN-
ZON
+
Ph
Ar-
Ar
then proton
H
NO2
transfer
Ph
Ph
hydrogen-bond
соmplex
Transcribed Image Text:Reaction Scheme: ÇF3 ÇF3 HN- 10 mol % urea NO2 + Ph CH2CI2, 23 °C CF3CH2OH, 24 h 43% yield F3C° `CF3 Ph ZON urea catalyst 1. During the first part of the mechanism in the reaction above, the catalyst forms a complex using hydrogen bonds. On the lines below the catalyst and the nitro alkene, label them as the Lewis Acid and/or Lewis Base. Ar Ar HN- ZON + Ph Ar- Ar then proton H NO2 transfer Ph Ph hydrogen-bond соmplex
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