In two parts, outline the Electrophilic aromatic substitution for the nitration of benzene using nitric acid and sulfuric acid: A) In part I, using the curved arrow formalism, outline a mechanism for the formation of the nitronium ion, NO2+ starting from nitric acid, HNO3 and sulfuric acid, H2SO4. Do not forget to show all of the formal charges for each atom that is not zero in this mechanism. B) Starting from the nitronium ion that you generated in part “a” from above, outline the Electrophilic Aromatic Substitution of this ion with benzene. ### Mechanisms:1. **In two parts, outline the Electrophilic Aromatic Substitution for the nitration of benzene using nitric acid and sulfuric acid:** a) In part I, using the curved arrow formalism, outline a mechanism for the formation of the nitronium ion, \( \text{NO}_2^+ \), starting from nitric acid, \( \text{HNO}_3 \), and sulfuric acid, \( \text{H}_2\text{SO}_4 \). Do not forget to show all of the formal charges for each atom that is not zero in this mechanism. b) Starting from the nitronium ion that you generated in part "a" from above, outline the Electrophilic Aromatic Substitution of this ion with benzene.

Nitration of benzene involves following three steps 1. Generation of Electrophile (Nitronium ion) 2.…

Answered: In two parts, outline the Electrophilic…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

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In two parts, outline the Electrophilic aromatic substitution for the nitration of benzene using nitric acid and sulfuric acid:

A) In part I, using the curved arrow formalism, outline a mechanism for the formation of the nitronium ion, NO2+ starting from nitric acid, HNO3 and sulfuric acid, H2SO4. Do not forget to show all of the formal charges for each atom that is not zero in this mechanism.

B) Starting from the nitronium ion that you generated in part “a” from above, outline the Electrophilic Aromatic Substitution of this ion with benzene.

### Mechanisms:

1. **In two parts, outline the Electrophilic Aromatic Substitution for the nitration of benzene using nitric acid and sulfuric acid:**

a) In part I, using the curved arrow formalism, outline a mechanism for the formation of the nitronium ion, \( \text{NO}_2^+ \), starting from nitric acid, \( \text{HNO}_3 \), and sulfuric acid, \( \text{H}_2\text{SO}_4 \). Do not forget to show all of the formal charges for each atom that is not zero in this mechanism.

b) Starting from the nitronium ion that you generated in part "a" from above, outline the Electrophilic Aromatic Substitution of this ion with benzene.

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