(a) For the precipitation reaction: A+ + B– AB(s)Calculate the value of the equilibrium constant for 99.99% conversion to AB atthe equivalence point, assuming that the analyte content is 5.00 mmole and thetotal volume at the equivalence point is 100.00 mL.(b) What factors affect end-point sharpness in a precipitation titration? Explain.(c) Explain briefly why silver nitrate is an important reagent used in precipitationtitrations.(d) Mohr Method, Volhard Method and Fajans Method are commonly used for thevolumetric analysis of chlorides. Distinguish the three methods in terms of thetitrants and indicators used, and how the titrations are carried out.
(a) For the precipitation reaction: A+ + B– AB(s)Calculate the value of the equilibrium constant for 99.99% conversion to AB atthe equivalence point, assuming that the analyte content is 5.00 mmole and thetotal volume at the equivalence point is 100.00 mL.(b) What factors affect end-point sharpness in a precipitation titration? Explain.(c) Explain briefly why silver nitrate is an important reagent used in precipitationtitrations.(d) Mohr Method, Volhard Method and Fajans Method are commonly used for thevolumetric analysis of chlorides. Distinguish the three methods in terms of thetitrants and indicators used, and how the titrations are carried out.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(a) For the precipitation reaction: A+ + B– AB(s)
Calculate the value of the equilibrium constant for 99.99% conversion to AB at
the equivalence point, assuming that the analyte content is 5.00 mmole and the
total volume at the equivalence point is 100.00 mL.
(b) What factors affect end-point sharpness in a precipitation titration? Explain.
(c) Explain briefly why silver nitrate is an important reagent used in precipitation
titrations.
(d) Mohr Method, Volhard Method and Fajans Method are commonly used for the
volumetric analysis of chlorides. Distinguish the three methods in terms of the
titrants and indicators used, and how the titrations are carried out.
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