A 250-mL buffer solution contains 0.0510 mole of KH2PO4 and 0.0875 mole of K2HPO4. (a) Calculate the molar concentrations of H2PO4–and HPO42–, respectively, in thesolution. (b) What is the pH of the solution? (H2PO4– has Ka = 6.2 x 10–8) (c) Write a net ionic equation for the buffering reaction against a strong acid by this buffer. (d) If 0.012 mole of hydrochloric acid (HCl) is added to the solution, create a reaction table to show the buffering reaction and calculate the molar concentration of H2PO4–and HPO42–, respectively, in the resulting solution after the buffering reaction. (e) What is the pH of the resulting solution?

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A 250-mL buffer solution contains 0.0510 mole of KH2PO4 and 0.0875 mole of K2HPO4.

(a) Calculate the molar concentrations of H2PO4and HPO42–, respectively, in thesolution.

(b) What is the pH of the solution? (H2PO4has Ka = 6.2 x 10–8)

(c) Write a net ionic equation for the buffering reaction against a strong acid by this buffer.

(d) If 0.012 mole of hydrochloric acid (HCl) is added to the solution, create a reaction table to show the buffering reaction and calculate the molar concentration of H2PO4and HPO42–, respectively, in the resulting solution after the buffering reaction.

(e) What is the pH of the resulting solution?

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