A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and E. The complex [MD6]³+ was found to be highly paramagnetic while the complex [ME6]³ was weakly paramagnetic. Further studies on [ME6]³- revealed the weak paramagnetism of the complex arises from the presence of a single unpaired electron. From these pieces of information, answer the following: Hybridization of M³+ in [MD]³+ (No need to write the number of orbitals as superscripts, e.g., sp3): Hybridization of M³+ in [MD]³- (No need to write the number of orbitals as superscripts, e.g., sp3): Identity of M (No need to write the charge; just write the symbol, e.g. Au): Identity of ligand D: [Choose your answer: water, carbon monoxide, ethylenediamine (en)] Identity of ligand E: [Choose your answer: oxalate, bromide, cyanide]
A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and E. The complex [MD6]³+ was found to be highly paramagnetic while the complex [ME6]³ was weakly paramagnetic. Further studies on [ME6]³- revealed the weak paramagnetism of the complex arises from the presence of a single unpaired electron. From these pieces of information, answer the following: Hybridization of M³+ in [MD]³+ (No need to write the number of orbitals as superscripts, e.g., sp3): Hybridization of M³+ in [MD]³- (No need to write the number of orbitals as superscripts, e.g., sp3): Identity of M (No need to write the charge; just write the symbol, e.g. Au): Identity of ligand D: [Choose your answer: water, carbon monoxide, ethylenediamine (en)] Identity of ligand E: [Choose your answer: oxalate, bromide, cyanide]
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 73QRT
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Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.
Question
![2.
A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and
E. The complex [MD6]³+ was found to be highly paramagnetic while the complex [ME6]³ was weakly
paramagnetic. Further studies on [ME]³- revealed the weak paramagnetism of the complex arises
from the presence of a single unpaired electron. From these pieces of information, answer the
following:
3+
Hybridization of M³+ in [MD]³+ (No need to write the number of orbitals as superscripts, e.g., sp3):
Hybridization of M³+ in [MD6]³- (No need to write the number of orbitals as superscripts, e.g., sp3):
Identity of M (No need to write the charge; just write the symbol, e.g. Au):
Identity of ligand D: [Choose your answer: water, carbon monoxide, ethylenediamine (en)]
Identity of ligand E: [Choose your answer: oxalate, bromide, cyanide]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fcc61e6f9-1283-4c33-8aac-5d95a690c4e7%2F69f62816-0254-4cb9-bb89-0304c27b0dd3%2Faj30bf_processed.png&w=3840&q=75)
Transcribed Image Text:2.
A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and
E. The complex [MD6]³+ was found to be highly paramagnetic while the complex [ME6]³ was weakly
paramagnetic. Further studies on [ME]³- revealed the weak paramagnetism of the complex arises
from the presence of a single unpaired electron. From these pieces of information, answer the
following:
3+
Hybridization of M³+ in [MD]³+ (No need to write the number of orbitals as superscripts, e.g., sp3):
Hybridization of M³+ in [MD6]³- (No need to write the number of orbitals as superscripts, e.g., sp3):
Identity of M (No need to write the charge; just write the symbol, e.g. Au):
Identity of ligand D: [Choose your answer: water, carbon monoxide, ethylenediamine (en)]
Identity of ligand E: [Choose your answer: oxalate, bromide, cyanide]
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