A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and E. The complex [MD6]³+ was found to be highly paramagnetic while the complex [ME6]³ was weakly paramagnetic. Further studies on [ME6]³- revealed the weak paramagnetism of the complex arises from the presence of a single unpaired electron. From these pieces of information, answer the following: Hybridization of M³+ in [MD]³+ (No need to write the number of orbitals as superscripts, e.g., sp3): Hybridization of M³+ in [MD]³- (No need to write the number of orbitals as superscripts, e.g., sp3): Identity of M (No need to write the charge; just write the symbol, e.g. Au): Identity of ligand D: [Choose your answer: water, carbon monoxide, ethylenediamine (en)] Identity of ligand E: [Choose your answer: oxalate, bromide, cyanide]

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 73QRT
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2.
A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and
E. The complex [MD6]³+ was found to be highly paramagnetic while the complex [ME6]³ was weakly
paramagnetic. Further studies on [ME]³- revealed the weak paramagnetism of the complex arises
from the presence of a single unpaired electron. From these pieces of information, answer the
following:
3+
Hybridization of M³+ in [MD]³+ (No need to write the number of orbitals as superscripts, e.g., sp3):
Hybridization of M³+ in [MD6]³- (No need to write the number of orbitals as superscripts, e.g., sp3):
Identity of M (No need to write the charge; just write the symbol, e.g. Au):
Identity of ligand D: [Choose your answer: water, carbon monoxide, ethylenediamine (en)]
Identity of ligand E: [Choose your answer: oxalate, bromide, cyanide]
Transcribed Image Text:2. A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and E. The complex [MD6]³+ was found to be highly paramagnetic while the complex [ME6]³ was weakly paramagnetic. Further studies on [ME]³- revealed the weak paramagnetism of the complex arises from the presence of a single unpaired electron. From these pieces of information, answer the following: 3+ Hybridization of M³+ in [MD]³+ (No need to write the number of orbitals as superscripts, e.g., sp3): Hybridization of M³+ in [MD6]³- (No need to write the number of orbitals as superscripts, e.g., sp3): Identity of M (No need to write the charge; just write the symbol, e.g. Au): Identity of ligand D: [Choose your answer: water, carbon monoxide, ethylenediamine (en)] Identity of ligand E: [Choose your answer: oxalate, bromide, cyanide]
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