a) Transition metal complexes are highly likely to be colored because of the size of the energy gap within the d orbitals and the number of electrons. In ruby, the red color of ruby is attributed to a small amount of Cr* substituting into AlżO3 which is made up of shared AIO6 octahedra. Provide a hypothesis for the origin of the red color observed in ruby. Red pigments tend to be rare. If you had to design a new material that b) had an approximate bandgap that would absorb green, what ideas do you need to employ to find a new semiconductor that does not contain Cd, Hg or Pb as one of the components (see last lecture for ideas).

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transition metal complexes are highly likely to be colored because of
a)
the size of the energy gap within the d orbitals and the number of electrons. In ruby,
the red color of ruby is attributed to a small amount of Cr³* substituting into Al2O3 which is
made up of shared AIO, octahedra. Provide a hypothesis for the origin of the red color
observed in ruby.
Red pigments tend to be rare. If you had to design a new material that
b)
had an approximate bandgap that would absorb green, what ideas do you need to
employ to find a new semiconductor that does not contain Cd, Hg or Pb as one of
the components (see last lecture for ideas).
Transcribed Image Text:Transition metal complexes are highly likely to be colored because of a) the size of the energy gap within the d orbitals and the number of electrons. In ruby, the red color of ruby is attributed to a small amount of Cr³* substituting into Al2O3 which is made up of shared AIO, octahedra. Provide a hypothesis for the origin of the red color observed in ruby. Red pigments tend to be rare. If you had to design a new material that b) had an approximate bandgap that would absorb green, what ideas do you need to employ to find a new semiconductor that does not contain Cd, Hg or Pb as one of the components (see last lecture for ideas).
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