Determine the CFSE in terms of A. and P for the following complexes: W a) [Fe(CN)6]4 b) [Ru(NH3)6]³+ c) [CoClBr(C2O4)2]³- > If there is a possibility of hi vs lo spin, explain which you choose. > For each, also report the spin only magnetic moment, = √n(n + 2) > Lastly, for each, state whether there will be a Jahn-Teller distortion and if it will be weak or strong.

Determine the CFSE in terms of A. and P for the following complexes: W a) [Fe(CN)6]4 b) [Ru(NH3)6]³+ c) [CoClBr(C2O4)2]³- > If there is a possibility of hi vs lo spin, explain which you choose. > For each, also report the spin only magnetic moment, = √n(n + 2) > Lastly, for each, state whether there will be a Jahn-Teller distortion and if it will be weak or strong.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Which of the following complexes is "inert" in regards to ligand substitution reactions? Group of answer choices [Co(NH3)3(H2O)3]2+ [Fe(CN)6]3- [V(bipy)2(OH)2]+ [FeCl6]3-
Consider the following complexes: [FeCl6]3- and [Fe(CN)6]3-, which possess very different magnetic moments. Give the calculated magnetic moment and CFSE for each. Would you expect either of the complexes to be distorted?
Does p-d mixing in electronic spectrum of [Mn(Br)4]2- occur due the pi-donating bromine ligand . Hence,what distinguishes the electronic spectrum of [Mn(OH2)6]2+ and [Mn(Br)4]2-.
The complex ion [Co(H₂O)]³+has a maximum absorbance wavelength of 600. nm. Calculate the crystal-field splitting energy in kilojoules per mole.
Which one of the following complexes could be resolved into a pair of optical isomers? (ox = C2O42-) a) [Co(NH3)4Cl2]+ b) [Co(CN)6]3- c) [Co(en)3]3+ d) [CoF6]3-
2 c) Make models of the two possible isomers of the [Co(NH3)4C12]+ ion. This is an octahedral complex. Sketch and name the isomers.
1. Tris(ethylenediamine) enantiomeric forms and assign their absolute configuration. Co(III) ([Co(en)3]³+) is a chiral complex. Draw its two
Provide the name of the coordination complex Na[CoCl4(NH3)2] b) Calculate the orbital multiplicity for a Cr3+ assuming it is a free ion (Not complex). c) Calculate the spin multiplicity of a metal ion Cr3+ assuming a high spin crystal field. d) Calculate the quantum number S for metal ion Cr 3+ assuming a high spin crystal field splitting. e) Predict the spin‐only magnetic moment at 25oC for [Fe(CN)6]4‐.
A complex with the following formula may possess which kind of isomerism? (Different letters A-F denote different ligands.) K[MA4B2]
3. Use ligand field theory to explain why [Ni(CN).]² is diamagnetic while [Ni(CI)4]²- is paramagnetic with a spin state of S = 1.
How do you determine value of delta in complexes? To be able approach a problem such as this Which one of each of the following pairs of complexes would have the highest value of Δ, the crystal-field splitting parameter:i) i) [Pd(NH3)6]4+ ii) [Ru(NH3)6]2+ iii) [Ru(H2O)6]2+ iv) [Fe(H2O)6]2+ v) [Cr(NH3)6]3+ vi) [Cr(H2O)6]3+ a) i), iii), and v) b) i), iv) and v) c) ii), iii) and vi) d) i), iv) and v)
The octahedral complex ion [CoF6]3– is paramagnetic with four unpaired 3d-electrons, whereas the complex ion [Co(CN)6]3– is diamagnetic. (a) Draw the crystal-field energy diagram for 3d-electrons in each complex. (b) Which ligand causes a larger splitting of d-orbitals in Co3+? (c) Which complex ion exhibits absorption spectrum with the longer max? Explain.