a) Draw two chair conformations and label the most stable conformation. For consistency between assignments, use the diagrams given. You may redraw but keep the orientation the same; otherwise, it becomes difficult for students to mark! I have added the Br to carbon 1 for the first chair conformation as a start. b) What is the dihedral angle between the chlorine atom and the methyl group in the most stable chair conformation. total for for correct drawing correct drawing for Br Br correct angle dihedral 1 angle = C/" 4 CH3 H *** : for identifying most stable

a) Draw two chair conformations and label the most stable conformation. For consistency between assignments, use the diagrams given. You may redraw but keep the orientation the same; otherwise, it becomes difficult for students to mark! I have added the Br to carbon 1 for the first chair conformation as a start. b) What is the dihedral angle between the chlorine atom and the methyl group in the most stable chair conformation. total for for correct drawing correct drawing for Br Br correct angle dihedral 1 angle = C/" 4 CH3 H *** : for identifying most stable

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: Draw cis and trans chair conformations for 1,4-dimethylcyclohexane. Comment on what happens when a…

A: The objective of this question is to draw cis and trans conformations of 1,4 dimethyl cyclohexane,…

Q: Answer the following parts (a-c) based on the Newman projection shown below. Draw the exact…

Q: For the the structure shown below, Part A) Draw the Newman projections and 3-D sawhorse structures…

A: In the given question we have to draw the Newman and sawhorse projection of the highest and lowest…

Q: 1. Compound 1 is one isomer of 1,3-dicholoro-2,4,6-triisopropylcyclohexane. a) Draw both chair…

A: Groups at axial position due to 1,3-diaxial interaction decrease the stability of cyclohexane…

Q: Br H₂C H H₂C Br Br. A D G CH₂ H,C. Br B CH₂ E Br CH₂ H Br. H₂C .. CH₂ F Br Br CH₂ To answer it…

A: To find out the most stable conformation of the given substituted cyclohexane first we shall draw…

Q: A) Draw both chair conformations (ring - flip isomers) of cis-2-methyl-cyclohexanol and…

A: Approach to solving the question:The question is about methylcyclohexanol methylcyclohexanoland…

Q: ОН menthol ОН isomenthol ОН neomenthol "ОН neoisomenthol

A: This question belong to Stereochemistry. To find stability first convert into chair conformation.

Q: 3. Draw all possible conformations for 2-methylbutane. Label all unfavorable interactions. Which…

Q: In box C, draw the Newman projection corresponding to the wedge/slash drawing below with the…

A: A question based on organic chemistry, which is to be accomplished.

Q: For the molecule shown below, draw both chair conformations and circle which is the lower energy…

A: The given molecule is (1S,2S,4S)-1,2,4-trifluorocyclohexane. It contains three fluorine group…

Q: Compare the following conformers of butan-2-ol. Match each conformer to their corresponding relative…

A: As the bulkyl group near to each other repulsion will increase energy will also increase 2 molecule…

Q: Answer the questions about the molecule shown here. H Br This molecule is shown in its most stable…

A: In Newman projection the stable conformation has bulkier group on front and back carbon at…

Q: 7. For each of these, draw the two conformers by adding the missing methyl and ethyl group. The…

A: The most stable isomer of given compound in chair form are given in step two.

Q: 3. Draw both conformers of each isomer below (molecules A-C). Circle the most stable conformer of…

A: Given are cyclohexane derivatives.In chair conformation, most stable conformation is one in which…

Q: 2. Convert the following hexagonal drawings into most stable chair conformation, and place them in…

A: We have find out the most stable chair confirmation of given compounds.

Q: Ship BOARD [Review Topica) [References) Use the References to access important values if needed for…

A: Here by using strain energy increment of groups in chair conformation , we have to determine the…

Q: raw the substituents in the specified locations on the given cyclohexane ring to show the most…

A: Given is chair conformation.Most stable chair conformation is one in which more groups are…

Q: Identify the correct Newman projection for each conformation of the compound below: Hint: You have…

A: The objective of this question is to draw both the chair conformers for the given projection, to…

Q: 1. For each of the following, draw the wedge and dash, the sawhorse and the Newman representation…

A: The conformation where there is least repulsion and maximum distance between the substituents is the…

Q: For 1-bromobutane draw Newman projections for the Syn-periplanar, conformation. the Anti- periplanar…

A: Newman projections of a molecule are conformation which are drawn by viewing along a particular…

Q: a) Draw the structure of 2,3-dimethyl butane

A: as per Q&A guidelines of portal I solve first question because it comes under multiple question…

Q: Draw all six confirmations for the molecule shown (three eclipsed and three staggered Newman…

A: In conformational isomers free rotation around single bond It show eclipsed , gauche and staggered…

Q: 2. Consider the molecule 1-Chlorobutane A) Draw all 7 Newman Projections for the molecule at C1-C2.…

A: The objective of this question is to explain the given conditions of 1-chlorobutane.

Q: What is the total strain energy of 2-methylpropane in an eclipsed conformation? (Use Newman…

A: Eclipsed Newman projection formula contain one H↔H eclipsed interaction and two H↔CH3 eclipsed…

Q: C. Using your molecular modeling kit, construct cis-1,4-dimethylcyclohexane. In the space below,…

A: The most stable conformation of cyclohexane is Chair conformation. Given molecule:…

Q: Indicate whether the pair of structures shown represent stereoisomers, constitutional isomers,…

Q: Consider the cyclohexane framework in a chair conformation, where carbon 1 has two substituents, X…

Q: 4. A). Draw a most stable form of Newman Projections of the following molecule for the carbon bond…

A: The given molecule is: Converting this structure to Newman Projection formula (along C1-C2 with C1…

Q: ecify the types of strain that destabilize the conformer shown below. Hint: All bonds not explicitly…

A: Torsional strain is the strain between the bonding electrons of two nearest bonds those don't shear…

Q: -१. HO Projection de Newman

Q: Consider the molecule 1-Chlorobutane A) Draw all 7 Newman Projections for the molecule at C1-C2. B)…

A: The objective of this question is to explain the given conditions of

Q: A. Using your molecular modeling kit, construct trans-1,4-dimethylcyclohexane. In the space below,…

A: In the chair conformation of cyclohexane, there are two types of hydrogen atoms, equatorial and…

Q: 6. Using Newman projections, draw each of the following molecules in its represented conformation…

Q: For the the structure shown below, Part A) Draw the Newman projections and 3-D sawhorse structures…

A: During Newman Projection drawing, look from C-2 to C-3. C-2 carbon contain two methyl (Me) groups…

Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

a) Draw two chair conformations and label the most stable conformation. For consistency between assignments,
use the diagrams given. You may redraw but keep the orientation the same; otherwise, it becomes difficult
for students to mark! I have added the Br to carbon 1 for the first chair conformation as a start.
b) What is the dihedral angle between the chlorine atom and the methyl group in the most stable chair
conformation.
total
for
for
correct drawing
correct drawing
for
Br
correct angle
Br
dihedral
1
angle =
CI"
4
CH3
H
***
: for
identifying most stable

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step 5

Step 6

Step 7

Trending now

This is a popular solution!

Step by step

Solved in 7 steps with 5 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

plzz answer this in detail, draw all possible chair conformation and mark the most stable one , please do with clean handwritting
Using Newman projections, draw each of the following molecules in its represented conformation with respect to the bond indicated. Use sqares to type in appropriate substitution.
a. b. For the following two pairs of molecules, (1) Draw out the chair conformation for each molecule, flip the ring if it is possible. (2) Compare both molecules to circle out which one is more stable. (3) Identify their relationship as: constitutional isomer, conformational isomer, stereoisomer or identical. (4) Find all the chiral center on each molecule and label them. Br.. Ax < and and H. H H Br H H
Please answer correctly and be sure of your answer
5. When cyclohexane is in the chair conformation, explain the difference between axial position and equatorial position. Hand-drawn the chair conformation and place the hydrogens (using different color) to axial and equatorial. 1 6. Draw a chair conformation of 1,4-dimethylcyclohexane in which on methyl group is equatorial and the other is axial. Draw a ring flip. From the drawing, determine whether it is a trans or cis. (Be sure to number all carbons for clarification).
1. 2. Draw both chair conformations of the structures below. Draw all hydrogen atoms. Circle the most stable conformation. H3C.,, H3C CH3 CH3
Do not give handwriting solution.
4. For the structure shown below, Part A) Draw the Newman projections and 3-D sawhorse structures corresponding to the lowest and highest energy conformations for rotation around the C2-C3 bond. Draw the Newman projections looking FROM THE C2 CARBON TO THE C3 CARBON (i.e. with the C2 carbon in the "front"). Part B) Determine the energy difference between the lowest and highest conformations, and be sure to clearly show each energy contribution that you are including in your calculation. Lowest Energy Conformation 3-D sawhorse Newman ECLIPSING Interactions Energy Difference: AB Energy kcal/mol H/H 1.0 H/Me 1.4 H/Et 1.5 H/Pr 1.6 H/1-Bu 3.0 Me / Me 2.6 Me/Et 2.7 Me/i-Pr 3.0 GAUCHE A Interactions Energy kcal/mol Me / Me 0.9 Me / Et 0.95 Me/i-Pr 1.1 Me/t-Bu 2.7 Et/Et 1.1 Et/i-Pr 1.6 Et/t-Bu 3.0 i-Pr/i-Pr 2.0 Highest Energy Conformation 3-D sawhorse Newman 1
help please answer in text form with proper workings and explanation for each and every part and steps with concept and introduction no AI no copy paste remember answer must be in proper format with all working
Do not give answer in image and hand writing