A diatomic molecule can be modeled as a rigid rotor with moment of inertia I and an electric dipole moment d along the axis of the rotor. The rotor is constrained to rotate in a plane, and a weak uniform electric field & lies in the plane. Write the classical Hamiltonian for the rotor, and find the unperturbed energy levels by quantizing the angular-momentum operator. Then treat the electric field as a perturbation, and find the first nonvanishing corrections to the energy levels.
A diatomic molecule can be modeled as a rigid rotor with moment of inertia I and an electric dipole moment d along the axis of the rotor. The rotor is constrained to rotate in a plane, and a weak uniform electric field & lies in the plane. Write the classical Hamiltonian for the rotor, and find the unperturbed energy levels by quantizing the angular-momentum operator. Then treat the electric field as a perturbation, and find the first nonvanishing corrections to the energy levels.
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![A diatomic molecule can be modeled as a rigid rotor with moment of inertia I and an
electric dipole moment d along the axis of the rotor. The rotor is constrained to rotate
in a plane, and a weak uniform electric field & lies in the plane. Write the classical
Hamiltonian for the rotor, and find the unperturbed energy levels by quantizing the
angular-momentum operator. Then treat the electric field as a perturbation, and find
the first nonvanishing corrections to the energy levels.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff75f0e5b-5c20-4fb0-a686-7a30b489a15b%2Fde54f23c-7c41-4ac1-8441-0f8194019c25%2F9kmj15_processed.png&w=3840&q=75)
Transcribed Image Text:A diatomic molecule can be modeled as a rigid rotor with moment of inertia I and an
electric dipole moment d along the axis of the rotor. The rotor is constrained to rotate
in a plane, and a weak uniform electric field & lies in the plane. Write the classical
Hamiltonian for the rotor, and find the unperturbed energy levels by quantizing the
angular-momentum operator. Then treat the electric field as a perturbation, and find
the first nonvanishing corrections to the energy levels.
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