(a) Based on the information provided, determine the structures of compounds. (b) Assign all peaks in 1 H and 13C NMR spectra of compounds

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(a) Based on the information provided, determine the structures of compounds.

(b) Assign all peaks in 1 H and 13C NMR spectra of compounds

13C NMR Spectrum
(100.0 MHz, Dyo sokuton)
DEPT
proton decoupled
200
160
120
80
40
O 8 (ppm)
'H NMR Spectrum
(400 MI. D20 solution)
expansions
Note: there are 4 protons
which euctange with
the Dgo solvent
4.3
4.1 ppm 36 34 ppm
1.3
1.1 ppm
HO and HOD
In solvent
10 9
8
7
5
4
3
2
1
8 (ppm)
6,
Transcribed Image Text:13C NMR Spectrum (100.0 MHz, Dyo sokuton) DEPT proton decoupled 200 160 120 80 40 O 8 (ppm) 'H NMR Spectrum (400 MI. D20 solution) expansions Note: there are 4 protons which euctange with the Dgo solvent 4.3 4.1 ppm 36 34 ppm 1.3 1.1 ppm HO and HOD In solvent 10 9 8 7 5 4 3 2 1 8 (ppm) 6,
Compound 3:
IR Spectrum
OKar disc
1627
1600
2000
V (cm")
4000
3000
1200
800
10야
57 75
Mass Spectrum
80
45
20
104 M* 119
CaHgNO3
40 80
120
160
200
240
280
m/e
yeed seg%
Transcribed Image Text:Compound 3: IR Spectrum OKar disc 1627 1600 2000 V (cm") 4000 3000 1200 800 10야 57 75 Mass Spectrum 80 45 20 104 M* 119 CaHgNO3 40 80 120 160 200 240 280 m/e yeed seg%
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