Based on the information provided, determine the structures of compounds. (b) Assign all peaks in 1 H and 13C NMR spectra of compounds

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(a) Based on the information provided, determine the structures of compounds.

(b) Assign all peaks in 1 H and 13C NMR spectra of compounds

13C NMR Spectrum
(50.0 MHz, COCI, solution)
DEPT
solvent
proton decoupled
200
160
120
80
40
O 8 (ppm)
H NMR Spectrum
(200 MHz. COCI, solution)
expansion
40
3.0
2.0
1.0 ppm
TMS
3 2 1
10
9
8.
6
8 (ppm)
Transcribed Image Text:13C NMR Spectrum (50.0 MHz, COCI, solution) DEPT solvent proton decoupled 200 160 120 80 40 O 8 (ppm) H NMR Spectrum (200 MHz. COCI, solution) expansion 40 3.0 2.0 1.0 ppm TMS 3 2 1 10 9 8. 6 8 (ppm)
IR Spectrum
(liquid fim)
1553
1387
4000
3000
2000
1600
1200
800
0.0
V (cm")
100
Mass Spectrum
0.5
UV spectrum
1.0
137.0 mg / 10 mis
path length: 0.2 om
solvent : ethanol
M*- 89 (* 1%)
C3H,NO2
1.5
40
80
120
160
200
240
280
200
350
250
300
A (nm)
m/e
ouequosge
yeed aseg jo
Lw a t
8 8 8 9 &
Transcribed Image Text:IR Spectrum (liquid fim) 1553 1387 4000 3000 2000 1600 1200 800 0.0 V (cm") 100 Mass Spectrum 0.5 UV spectrum 1.0 137.0 mg / 10 mis path length: 0.2 om solvent : ethanol M*- 89 (* 1%) C3H,NO2 1.5 40 80 120 160 200 240 280 200 350 250 300 A (nm) m/e ouequosge yeed aseg jo Lw a t 8 8 8 9 &
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