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(a) (b) (c) An atom has a non-degenerate electronic state 1000 cm-1 above a non degenerate electronic ground state. Determine: (i) the electronic partition function q at 1500 K; (ii) the relative population of the upper state at 1500 K; the mean electronic energy (E) at 1500 K; (iii) (iv) (EE) when T→∞. Determine the atomic partition function q for 35Cl atoms confined in a volume of 0.01 m³ at 1500 K, given that the 2P12 electronic state is four 900 cm-1 above the 2P3/2 electronic ground state. Justify any assumptic that you make. For a monatomic perfect gas with a non-degenerate electronic ground state show that at room temperature (s)-3KT/2. State any assumption that you make. USEFUL INFORMATION Relative isotopic mass: 35Cl 34.969.

(a) (b) (c) An atom has a non-degenerate electronic state 1000 cm-1 above a non degenerate electronic ground state. Determine: (i) the electronic partition function q at 1500 K; (ii) the relative population of the upper state at 1500 K; the mean electronic energy (E) at 1500 K; (iii) (iv) (EE) when T→∞. Determine the atomic partition function q for 35Cl atoms confined in a volume of 0.01 m³ at 1500 K, given that the 2P12 electronic state is four 900 cm-1 above the 2P3/2 electronic ground state. Justify any assumptic that you make. For a monatomic perfect gas with a non-degenerate electronic ground state show that at room temperature (s)-3KT/2. State any assumption that you make. USEFUL INFORMATION Relative isotopic mass: 35Cl 34.969.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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This is an old exam paper but I am unable to find the mark scheme to check my answer. Help would be very much appreciated.

4. Answer ALL parts. (a) An atom has a non-degenerate electronic state 1000 cm-¹ above a non- degenerate electronic ground state. Determine: (i) the electronic partition function q² at 1500 K; (ii) the relative population of the upper state at 1500 K; (iii) the mean electronic energy at 1500 K; (iv) (²) when T→∞. Determine the atomic partition function q for 35Cl atoms confined in a volume of 0.01 m³ at 1500 K, given that the 2P₁/2 electronic state is found 900 cm-1 above the 2P3/2 electronic ground state. Justify any assumptions that you make. For a monatomic perfect gas with a non-degenerate electronic ground state show that at room temperature (s) = 3kT/2. State any assumptions that you make. (b) (c) USEFUL INFORMATION Relative isotopic mass: 35Cl 34.969.
Transcribed Image Text:4. Answer ALL parts. (a) An atom has a non-degenerate electronic state 1000 cm-¹ above a non- degenerate electronic ground state. Determine: (i) the electronic partition function q² at 1500 K; (ii) the relative population of the upper state at 1500 K; (iii) the mean electronic energy at 1500 K; (iv) (²) when T→∞. Determine the atomic partition function q for 35Cl atoms confined in a volume of 0.01 m³ at 1500 K, given that the 2P₁/2 electronic state is found 900 cm-1 above the 2P3/2 electronic ground state. Justify any assumptions that you make. For a monatomic perfect gas with a non-degenerate electronic ground state show that at room temperature (s) = 3kT/2. State any assumptions that you make. (b) (c) USEFUL INFORMATION Relative isotopic mass: 35Cl 34.969.
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