A 5.850-g sample containing KCl and KClO4 was dissolved in sufficient water to give 250.00 mL of solution. A 50.00-mL portion of the solution required 43.94 mL of 0.0750 M AgNO3 in a Mohr titration. Next, a 25.00-mL portion of the original solution was treated with V₂(SO4)3 to reduce the perchlorate ion to chloride, 8 V³+ (aq) + C1O4 (aq) + 12 H₂O(l) → Cl(aq) +8 VO²+ (aq) + 8 H3O+ (aq) and the resulting solution was titrated with AgNO3. This titration required 38.06 mL of 0.0750 M AgNO3. What is the mass percent of KCl and KC1O4 in the mixture? % KCI % KC1O4

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### Determining the Mass Percent of KCl and KClO₄ in a Mixture

A 5.850-g sample containing KCl and KClO₄ was dissolved in sufficient water to give 250.00 mL of solution. A 50.00-mL portion of the solution required 43.94 mL of 0.0750 M AgNO₃ in a Mohr titration. 

Next, a 25.00-mL portion of the original solution was treated with V₂(SO₄)₃ to reduce the perchlorate ion to chloride. The reaction is as follows:

\[ 8 \, V^{3+} \,(aq) + \, ClO₄^- \, (aq) + \, 12 \, H_2O \, (l) \rightarrow Cl^- \, (aq) + \, 8 \, VO^{2+} \, (aq) + \, 8 \, H_3O^{+} \, (aq) \]

The resulting solution was titrated with AgNO₃. This titration required 38.06 mL of 0.0750 M AgNO₃. 

---

### Questions:
1. What is the mass percent of KCl in the mixture?
2. What is the mass percent of KClO₄ in the mixture?

---

\[ \boxed{ \% \, \text{KCl} } \]

\[ \boxed{ \% \, \text{KClO₄} } \]
Transcribed Image Text:### Determining the Mass Percent of KCl and KClO₄ in a Mixture A 5.850-g sample containing KCl and KClO₄ was dissolved in sufficient water to give 250.00 mL of solution. A 50.00-mL portion of the solution required 43.94 mL of 0.0750 M AgNO₃ in a Mohr titration. Next, a 25.00-mL portion of the original solution was treated with V₂(SO₄)₃ to reduce the perchlorate ion to chloride. The reaction is as follows: \[ 8 \, V^{3+} \,(aq) + \, ClO₄^- \, (aq) + \, 12 \, H_2O \, (l) \rightarrow Cl^- \, (aq) + \, 8 \, VO^{2+} \, (aq) + \, 8 \, H_3O^{+} \, (aq) \] The resulting solution was titrated with AgNO₃. This titration required 38.06 mL of 0.0750 M AgNO₃. --- ### Questions: 1. What is the mass percent of KCl in the mixture? 2. What is the mass percent of KClO₄ in the mixture? --- \[ \boxed{ \% \, \text{KCl} } \] \[ \boxed{ \% \, \text{KClO₄} } \]
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